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首页> 外文期刊>Environmental toxicology and chemistry >OCCURRENCE AND DISSIPATION OF BENZOTRIAZOLES AND BENZOTRIAZOLE ULTRAVIOLET STABILIZERS IN BIOSOLID-AMENDED SOILS
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OCCURRENCE AND DISSIPATION OF BENZOTRIAZOLES AND BENZOTRIAZOLE ULTRAVIOLET STABILIZERS IN BIOSOLID-AMENDED SOILS

机译:苯并三唑和苯并三唑紫外线稳定剂在生物碱改性土壤中的发生和消散

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摘要

Benzotriazoles (BTs) and benzotriazole ultraviolet (UV) stabilizers (BUVSs) are commonly used industrial and household chemicals, but little is known about their dissipation behavior in the soil environment associated with biosolid application. The authors investigated the occurrence and dissipation of 4 BTs (BT, 5-methyl-1H-benzotriazole [5-TT], 5-chloro-1H-benzotriazole [CBT], and 5,6-dimethyl-1H-benzotriazole [XT]) and 5 BUVSs (UV-326, UV-327, UV-328, UV-329, and UV-P) in biosolid-amended soil of 3 trial sites (Zhejiang, Hunan, and Shandong) in China following 2 treatments (treatment 1: a single application of biosolid; treatment 2: repeated application of biosolid). The results showed that except for CBT and XT, the other 7 compounds could be detected in most of the biosolid and biosolid-amended soils at levels of a few to tens of nanograms per gram and that the concentrations of the 7 compounds for treatment 2 were obviously higher than those for treatment 1. In the 1-yr monitoring of the Shandong site, 2 BTs (BT and 5-TT) and 5 BUVSs (UV-326, UV-327, UV-328, UV-329, and UV-P) were significantly dissipated in the biosolid-amended soils. The field half-lives of BT and 5-TT ranged from 217 d to 345 d, while those for the BUVSs ranged between 75 d and 218 d. The field half-lives of target compounds in soil were found to be comparable to the modeling results. The results suggest the persistence of BTs and BUVSs in soil environments with quite slow dissipation rates.
机译:苯并三唑(BTs)和苯并三唑紫外线(UV)稳定剂(BUVS)是常用的工业和日用化学品,但对于它们在生物固体施用相关的土壤环境中的耗散行为知之甚少。作者研究了4种BT(BT,5-甲基-1H-苯并三唑[5-TT],5-氯-1H-苯并三唑[CBT]和5,6-二甲基-1H-苯并三唑[XT])的发生和消散)和2种处理(处理)后在中国3个试验地点(浙江,湖南和山东)的生物固体改良土壤中的5个BUVS(UV-326,UV-327,UV-328,UV-329和UV-P) 1:单次施用生物固体;处理2:重复施用生物固体)。结果表明,除了CBT和XT外,在大多数生物固体和生物固体改良土壤中都可以检测到其他7种化合物,其含量为每克几十至数十毫微克,而用于处理2的7种化合物的浓度为明显高于治疗1。在山东地区的1年监测中,有2个BT(BT和5-TT)和5个BUVS(UV-326,UV-327,UV-328,UV-329和UV) -P)明显消散在生物固体改良土壤中。 BT和5-TT的半衰期为217 d至345 d,而BUVS的半衰期为75 d至218 d。发现目标化合物在土壤中的半衰期与模拟结果相当。结果表明BTs和BUVSs在土壤环境中的耗散率很慢。

著录项

  • 来源
    《Environmental toxicology and chemistry》 |2014年第4期|761-767|共7页
  • 作者单位

    State Key Laboratory of Organic Geochemistry, CAS Centre for Pearl River Delta Environmental Pollution and Control Research, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou, China;

    State Key Laboratory of Organic Geochemistry, CAS Centre for Pearl River Delta Environmental Pollution and Control Research, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou, China;

    Ministry of Agriculture Key Laboratory of Plant Nutrition and Nutrient Cycling, Institute of Agricultural Resources and Regional Planning, Chinese Academy of Agricultural Sciences, Beijing, China;

    State Key Laboratory of Organic Geochemistry, CAS Centre for Pearl River Delta Environmental Pollution and Control Research, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou, China;

    State Key Laboratory of Organic Geochemistry, CAS Centre for Pearl River Delta Environmental Pollution and Control Research, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou, China;

    State Key Laboratory of Organic Geochemistry, CAS Centre for Pearl River Delta Environmental Pollution and Control Research, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou, China;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);美国《化学文摘》(CA);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    Benzotriazole; Ultraviolet stabilizer; Biosolid application; Soil; Dissipation;

    机译:苯并三唑;紫外线稳定剂;生物固体应用;泥;耗散;

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