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首页> 外文期刊>Fibres & textiles in Eastern Europe >Flame Retardancy of Paper Obtained with Environmentally Friendly Agents
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Flame Retardancy of Paper Obtained with Environmentally Friendly Agents

机译：使用环保剂获得的纸张的阻燃性

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摘要

Flame retardancy was imparted through the addition of an organophosphorus agent which enhances paper utilisation and increases the value of paper products. For that purpose paper was impregnated with a solution containing aflame retardant agent, a binder and its catalyst, which was then linked during the curing step. N-hydroxymethyl-3-dimethylphos-phonpropionamide was used as the organophosphorus flame retardant (FR) agent with two types of binders: either melamine formaldehyde or citric acid. The use of a bonding agent is necessary in order to form covalent linkages between the FR agent and cellulose macromolecules. The first binder type implements an etherification mechanism which requires phosphoric acid for the catalysation. Second binder type implements esterification mechanism which requires phosphono based catalysts. Citric acid represents a new class of environmentally friendly agents, and as such is recommended for usage. A non-durable flame retardant based on boron compounds was used in the study for comparison. Flame retardancy was tested according to the ISO 6940 and 6941 methods, as well as with the limiting oxygen index (LOI) technique according to ASTM D 2863-97, while the tensile indices were measured according to ISO 1924-2.
机译：通过添加有机磷试剂赋予阻燃性，该有机磷试剂可提高纸张利用率并增加纸产品的价值。为此，将纸浸有含阻燃剂，粘合剂及其催化剂的溶液，然后在固化步骤中将其连接。 N-羟甲基-3-二甲基磷酸苯丙酰胺被用作具有两种粘合剂的有机磷阻燃剂（FR）：三聚氰胺甲醛或柠檬酸。为了在FR剂和纤维素大分子之间形成共价键，必须使用粘合剂。第一类粘合剂实现了醚化机理，该醚化机理需要磷酸来进行催化。第二种粘合剂类型实现酯化机理，这需要基于膦酰基的催化剂。柠檬酸代表了新型的环保剂，因此建议使用。在研究中使用了一种基于硼化合物的非耐久阻燃剂进行比较。根据ISO 6940和6941方法测试了阻燃性，并根据ASTM D 2863-97使用了极限氧指数（LOI）技术进行了测试，而拉伸指数则根据ISO 1924-2进行了测试。

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  • 来源
    《Fibres & textiles in Eastern Europe》 |2009年第3期|90-94|共5页
  • 作者

    Drago Katovic; Sandra Bischof Vukusic; Sandra Flincec Grgac; Branka Lozo; Dubravko Banic;

  • 作者单位

    Faculty of Textile Technology, University of Zagreb Department of Textile Chemistry & Ecology, Savska 16/5,10 000 Zagreb, Croatia;

    Faculty of Textile Technology, University of Zagreb Department of Textile Chemistry & Ecology, Savska 16/5,10 000 Zagreb, Croatia;

    Faculty of Textile Technology, University of Zagreb Department of Textile Chemistry & Ecology, Savska 16/5,10 000 Zagreb, Croatia;

    Faculty of Graphic Art, University of Zagreb Department of Materials in Printing Technology, Savska 16/5,10 000 Zagreb, Croatia;

    Faculty of Graphic Art, University of Zagreb Department of Materials in Printing Technology, Savska 16/5,10 000 Zagreb, Croatia;

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  • 正文语种 eng
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  • 关键词

    paper; flame retardant finishing; organophosphorus agent; citric acid; LOI;

    机译：纸;阻燃整理;有机磷剂柠檬酸;意向书;

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