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Direct conversion of biomass to platform chemicals, catalyzed using a deep eutectic solvent of N,N diethyl ethanol ammonium chloride-oxalic acid in a microwave reactor

机译:在微波反应器中,使用N,N二乙基乙醇氯化铵-草酸的低共熔溶剂催化将生物质直接转化为平台化学品

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Nowadays, the production of platform chemicals from cellulose is found as promising way to obtain valuable products from renewable sources instead of fossil fuel sources. In this study, conversion of cellulose into valuable products by using deep eutectic solvent as catalyst has been studied. The performance of deep eutectic solvent formed by N,N diethylethanol ammonium chloride and oxalic acid was evaluated for the conversion of cellulose in the microwave reactor. Deep eutectic solvent can be easily formed by mixing hydrogen bond acceptor and hydrogen bond donor at specified ratio. Deep eutectic solvents are found promising for processing of biomass and also to obtain ecofriendly systems due to the green nature of deep eutectic solvents (DES). This study show the applicability of DES formed by N,N diethyl ethanol ammonium chloride and oxalic acid in the conversion of cellulose at a temperature of 150, 160 and 170 degrees C and 2.5, 5.0 and 7.5 reaction time. The maximum C efficiency was achieved as 38.4% at 170 degrees C and 5 min reaction time in microwave reactor.
机译:如今,发现从纤维素生产平台化学品是从可再生资源而非化石燃料源获得有价值产品的有前途的方式。在这项研究中,已经研究了通过使用低共熔溶剂作为催化剂将纤维素转化为有价值的产品的方法。评价了由N,N二乙基乙醇氯化铵和草酸形成的深共熔溶剂在微波反应器中纤维素转化的性能。通过以指定比例混合氢键受体和氢键供体,可以容易地形成深共晶溶剂。由于深共晶溶剂(DES)的绿色特性,发现深共晶溶剂有望用于生物质的处理以及获得生态友好的系统。这项研究表明,N,N二乙基乙醇氯化铵和草酸形成的DES在150、160和170摄氏度,2.5、5.0和7.5反应时间的纤维素转化中的适用性。在微波反应器中,在170摄氏度和5分钟的反应时间下,最大C效率达到38.4%。

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