Solid-liquid equilibria under high pressure of pure fatty acid methyl esters

Assamoi Cedric Kouakou; Katell Le Mapihan; Jerome Pauly

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Solid-liquid equilibria under high pressure of pure fatty acid methyl esters

机译：纯脂肪酸甲酯在高压下的固液平衡

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The melting temperature of fatty acid methyl esters (FAMEs) have been measured both at atmospheric pressure by using a μDSC calorimeter and at high pressure (up to 80 MPa) thanks to a dedicated microscope. The values obtained at atmospheric pressure have been compared with literature data. The influence of the chain structure on the melting temperatures has been discussed, as well as the slopes of the liquid-solid transition curves in the (T, P) diagram. The experimental results have efficiently allowed predicting the solid molar volume and consequently, the difference between the volume in liquid and solid phases has been evaluated.

机译：借助专用的显微镜，在大气压下使用μDSC量热计和在高压（最高80 MPa）下均可测量脂肪酸甲酯（FAME）的熔融温度。将在大气压下获得的值与文献数据进行了比较。讨论了链结构对熔融温度的影响，以及（T，P）图中液固转变曲线的斜率。实验结果有效地预测了固体的摩尔体积，因此，对液相和固相之间的体积差异进行了评估。

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来源
《Fuel》 |2013年第7期|297-302|共6页
作者
Assamoi Cedric Kouakou; Katell Le Mapihan; Jerome Pauly;
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作者单位

Laboratoire des Fluides Complexes et leurs Reservoirs, UMR 5150, BP 1155, 640 73 Pau Cedex, France,Total Raffinage Chimie, CERT, BP 27, 76700 Harfleur, France;

Total Raffinage Chimie, CERT, BP 27, 76700 Harfleur, France;

Laboratoire des Fluides Complexes et leurs Reservoirs, UMR 5150, BP 1155, 640 73 Pau Cedex, France;

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收录信息美国《科学引文索引》(SCI);美国《工程索引》(EI);
原文格式 PDF
正文语种 eng
中图分类
关键词
Solid-liquid equilibrium; High-pressure; Phase diagrams; Fatty acid methyl esters;

机译：固液平衡;高压力;相图;脂肪酸甲酯;

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2. Measurement and modelling of solid-liquid equilibria, density and viscosity of fatty acid methyl or ethyl esters [J] . Gahlyan Suman, Maken Sanjeev, Park So-Jin Journal of Molecular Liquids . 2020,第1期

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4. SEPARATION OF FATTY ACID METHYL ESTERS AND TOCOPHEROLS WITH SUPERCRITICAL CO_2 - PHASE EQUILIBRIA AND FRACTIONATION EXPERIMENTS [C] . Tao Fang, Motonobu Goto, Mitsuru Sasaki, Italian Conference on Supercritical Fluids and Their Applications . 2004

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5. Process investigation and optimization of heterogeneous catalystic decarboxylation of fatty acids and fatty acid methyl esters for renewable diesel production. [D] . Wang, Dongyun. 2014

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6. Fat-deficiency disease of rats. The relative curative potencies of methyl linoleate and methyl arachidonate with a note on the action of the methyl esters of fatty acids from cod liver oil [O] . Eleanor Margaret Hume, Leslie Charles Alfred Nunn, Ida Smedley-Maclean, 1940

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7. Liquid-vapour equilibria of the methyl esters of alkanoic acids: vapour pressures as a function of temperature and standard thermodynamic function changes. [O] . van Genderen, A.C.G., van Miltenburg, J.C., Blok, J.G., 2002

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Solid-liquid equilibria under high pressure of pure fatty acid methyl esters

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