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Molecular Dynamics in Strong Laser Fields

机译:强激光场中的分子动力学

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摘要

One of the goals for strong field physics is imaging the dynamics of the quantum systems, and in case of molecules, there is strong interest in imaging of the electron rearrangement during chemical reactions. Strong field ionization of molecules has many attractive features that make this process a candidate tool for strong field imaging of transient states and chemical reactions. In this paper, we present analysis of ionization dependence on orientation of molecular axis with respect to polarization of the electric field of the laser. By considering several examples of molecules at their equilibrium internuclear distances and an example of the simplest chemical reaction, namely, the dissociation of diatomic molecule, we present how symmetries of the molecular orbitals influence the alignment-dependent ionization and how this dependence can be used to follow molecular dynamics using strong field multiphoton ionization.
机译:强场物理学的目标之一是对量子系统的动力学进行成像,对于分子,对化学反应过程中电子重排的成像引起了极大的兴趣。分子的强场电离具有许多吸引人的功能,使该过程成为瞬态和化学反应的强场成像的候选工具。在本文中,我们介绍了电离对分子轴取向与激光电场极化的相关性的分析。通过考虑处于平衡核间距的分子的几个例子以及最简单的化学反应(即双原子分子的解离)的例子,我们介绍了分子轨道的对称性如何影响取向依赖性电离,以及如何使用这种依赖性使用强场多光子电离遵循分子动力学。

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