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Analyzing the defect structure of CuO-Doped PZT and KNN piezoelectrics from electron paramagnetic resonance

机译:从电子顺磁共振分析掺杂CuO的PZT和KNN压电材料的缺陷结构

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摘要

The defect structure for copper-doped sodium potassium niobate (KNN) ferroelectrics has been analyzed with respect to its defect structure. In particular, the interplay between the mutually compensating dimeric (CuNb-VO) and trimeric (VO-CuNb-VO) defect complexes with 180?? and non-180?? domain walls has been analyzed and compared to the effects from (Cu - VO)x?? dipoles in CuO-doped lead zirconate titanate (PZT). Attempts are made to relate the rearrangement of defect complexes to macroscopic electromechanical properties.
机译:铜掺杂铌酸钾钠(KNN)铁电体的缺陷结构已针对其缺陷结构进行了分析。特别是,相互补偿的二聚体(Cu Nb -V O )和三聚体(V O -Cu Nb < / sub> -V O )缺陷复合物,含180?和非180?分析了畴壁并与(Cu-V O ) x ?? CuO掺杂的锆钛酸铅(PZT)中的偶极子。尝试将缺陷配合物的重排与宏观机电性能相关。

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