Predicting the Phase Stability of Sc_(1-x)Ln_xPO_4 (Ln = Gd-Lu, Y) Zircon-Structured Solid Solutions

Getman E. I.; Radio S. V.; Ardanova L. I.

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Predicting the Phase Stability of Sc_(1-x)Ln_xPO_4 (Ln = Gd-Lu, Y) Zircon-Structured Solid Solutions

机译：预测Sc_（1-x）Ln_xPO_4（Ln = Gd-Lu，Y）锆石结构固溶体的相稳定性

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The energies of mixing (interaction parameters) in the Sc1-x Ln (x) PO4 (Ln = Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Y) systems have been calculated using Urusov's crystal energy theory of isomorphous substitutions. The decomposition (stability) temperatures of the solid solutions have been plotted against the atomic number of the rare-earth elements at x = 0.01, 0.03, 0.05, 0.10, 0.20, and 0.50. The present results can be helpful in a search for host and activator compositions for new luminescence, laser, and other materials based on the zircon-structured rare-earth orthophosphates.

机译：Sc1-x Ln（x）PO4（Ln = Gd，Tb，Dy，Ho，Er，Tm，Yb，Lu，Y）系统中的混合能量（相互作用参数）已使用Urusov的同构晶体能量理论进行了计算换人。绘制了固溶体的分解（稳定性）温度与稀土元素在x = 0.01、0.03、0.05、0.10、0.20和0.50时的原子序数的关系图。目前的结果有助于寻找基于锆石结构稀土正磷酸盐的新型发光材料，激光和其他材料的主体和活化剂组合物。

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来源
《Inorganic materials》 |2018年第6期|596-600|共5页
作者
Getman E. I.; Radio S. V.; Ardanova L. I.;
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作者单位

Vasyl Stus Donetsk Natl Univ, Vul 600 Richchia 21, UA-21021 Vinnytsia, Ukraine;

Vasyl Stus Donetsk Natl Univ, Vul 600 Richchia 21, UA-21021 Vinnytsia, Ukraine;

Minnesota State Univ, Dept Chem & Geol, 241 Ford Hall, Mankato, MN 56001 USA;

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收录信息美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);
原文格式 PDF
正文语种 eng
中图分类
关键词
solid solution; orthophosphate; zircon structure; energy of mixing;

机译：固溶体;正磷酸盐;锆石结构;混合能;

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Predicting the Phase Stability of Sc_(1-x)Ln_xPO_4 (Ln = Gd-Lu, Y) Zircon-Structured Solid Solutions

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