Electrical and Optical Properties of Al~(3+)-Intercalated InSe and GaSe

V. B. Boledzyuk; Z. D. Kovalyuk; M. N. Pyrlya; S. G. Barbutsa

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Electrical and Optical Properties of Al~(3+)-Intercalated InSe and GaSe

机译：Al〜（3+）嵌入InSe和GaSe的电学和光学性质

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We have studied the electrochemical, electrical, and optical properties of aluminum-intercalated indium and gallium monoselenides. Electron probe X-ray microanalysis data demonstrate that aluminum ions are incorporated into the host together with their solvation shell. Such Al~(3+) incorporation leads to changes in the electrical properties of InSe layered crystals when the intercalate concentration reaches the level N_(Al) ～ 10~(20) to 10~(21) cm~(-3), which corresponds to the formation of the final reaction product [ Al_x~+(R-PC)_y]InSe~- (where PC stands for propylene carbonate). At 77 K, the energy position of the exciton peak in the Al_xInSe and Al_xGaSe intercalation compounds is a nonmonotonic function of aluminum concentration.

机译：我们已经研究了铝嵌入的铟和镓单硒化物的电化学，电学和光学性质。电子探针X射线微分析数据表明，铝离子连同其溶剂化壳一起被掺入宿主中。当插层浓度达到N_（Al）〜10〜（20）至10〜（21）cm〜（-3）时，这种Al〜（3+）的引入会导致InSe层状晶体的电学性质发生变化。对应于最终反应产物[Al_x〜+（R-PC）_y] InSe〜-的形成（其中PC代表碳酸亚丙酯）。在77 K时，Al_xInSe和Al_xGaSe插层化合物中激子峰的能量位置是铝浓度的非单调函数。

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《Inorganic materials》 |2013年第1期|22-27|共6页
作者
V. B. Boledzyuk; Z. D. Kovalyuk; M. N. Pyrlya; S. G. Barbutsa;
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作者单位

Frantsevich Institute of Materials Science Problems (Chernivtsi Branch), National Academy of Sciences of Ukraine, ul. Vilde 5, Chernivtsi, 58001 Ukraine;

Frantsevich Institute of Materials Science Problems (Chernivtsi Branch), National Academy of Sciences of Ukraine, ul. Vilde 5, Chernivtsi, 58001 Ukraine;

Frantsevich Institute of Materials Science Problems (Chernivtsi Branch), National Academy of Sciences of Ukraine, ul. Vilde 5, Chernivtsi, 58001 Ukraine;

Frantsevich Institute of Materials Science Problems (Chernivtsi Branch), National Academy of Sciences of Ukraine, ul. Vilde 5, Chernivtsi, 58001 Ukraine;

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收录信息美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);
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Electrical and Optical Properties of Al~(3+)-Intercalated InSe and GaSe

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