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首页> 外文期刊>International journal of hydrogen energy >A new electronic theory of pericyclic chemistry and aromaticity is proposed: The Cplex-isoelectronic theory. Consistent with Santilli's hadronic chemistry
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A new electronic theory of pericyclic chemistry and aromaticity is proposed: The Cplex-isoelectronic theory. Consistent with Santilli's hadronic chemistry

机译：提出了一种新的关于周环化学和芳香性的电子理论：Cplex-等电子学理论。与Santilli的强子化学一致

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A new electronic theory of pericyclic chemistry and aromaticity, in line with the Robinson/Ingold electronic theory, is proposed. It is referred to as the Cplex-isoelectronic theory. This represents the first successful theory that is not based on quantum mechanics. There are three assumptions in this theory (1) ADEP, (2) SDEP and (3) SDSE. The ADEP assumption refers to isoelectron pairs moving in an antiperiplanar mode in relation to the plane of the molecule. SDEP relates to isoelectron pairs moving in a synperiplanar mode and SDSE refers to single isoelectrons moving in a synperiplanar mode. These assumptions are deduced from nucleophilic, radical addition, S_N2 and S_N2′ reactions and the anomeric effect. Application of the ADEP concept to pericyclic reactions is supported by Complexity theory and backed up by direct empirical evidence from 1,3-dipolar cycloaddition reactions involving nitronates and by its ability to predict the experimental data. The heavy atom effect provides experimental evidence for the SDSE mode in pericyclic reactions. The HOMO Diels-Alder is consistent with the SDEP concept. Evidence for the assumptions in aromatic compounds is found in the observation of a diamagnetic ring current in the presence of an applied field and in the applicability of the Biot-Savart law. The Cplex-isoelectronic theory makes different predictions from the present quantum chemical methods in some cases, namely the existence of suprafacial concerted thermal [2 + 2], [4 + 4], [6 + 2] and [6 + 6] cycloadditions, suprafacial concerted photochemical [4 + 2] and [6 + 4] cycloadditions, stepwise [2 + 2 + 2] cycloadditions of ethyne, diamagnetic ring currents for some cyclic systems with Ann electrons. The available empirical evidence is consistent with these predictions. This finding is consistent with Santilli's hadronic chemistry which proposes that the present quantum chemical theories require the addition of a small correction factor for molecules with two or more electrons.
机译：根据Robinson / Ingold电子理论，提出了一种新的关于周环化学和芳香性的电子理论。它被称为Cplex等电子理论。这代表了第一个不基于量子力学的成功理论。该理论有三个假设：（1）ADEP，（2）SDEP和（3）SDSE。 ADEP假设是指等电子对相对于分子平面以反周平面模式运动。 SDEP涉及以同上平面模式移动的等电子对，SDSE指以同上平面模式移动的单个等电子。这些假设是从亲核，自由基加成，S_N2和S_N2'反应以及端基异构效应得出的。 ADEP概念在环周反应中的应用得到复杂性理论的支持，并得到涉及硝酸盐的1,3-偶极环加成反应的直接经验证据以及其预测实验数据的能力作为后盾。重原子效应为环周反应中的SDSE模式提供了实验证据。 HOMO Diels-Alder与SDEP概念一致。芳香化合物中的假设证据可在存在外加磁场的情况下通过观察反磁环电流以及Biot-Savart定律的适用性来找到。在某些情况下，Cplex等电子学理论对目前的量子化学方法做出了不同的预测，即存在表面协同热[2 + 2]，[4 + 4]，[6 + 2]和[6 + 6]环加成，超表面一致的光化学[4 + 2]和[6 + 4]环加成，乙炔的逐步[2 + 2 + 2]环加成，某些带有Ann电子的环状系统的反磁性环电流。现有的经验证据与这些预测是一致的。这一发现与桑提利的强子化学相符，后者提出，当前的量子化学理论需要为带有两个或多个电子的分子增加一个小的校正因子。

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