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GENERATION OF ARAGONITE NANOCRYSTALS IN A MAGNETIZED WATER FLOW

机译:磁化水流中生成文石纳米晶

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It is known that polymorphism of calcium carbonate CaCO3 admits the formation of crystals in three different phases: vaterite, aragonite, and calcite. This work gives explanation of one of the effects noted on magnetization of water flow, i.e., the prevailing composition of a suspension in the form of aragonite nanocrystals. According to the model proposed earlier on the basis of the nanomechanics approaches, a magnetic field accelerates coagulation of nanosized critical nuclei in a supersaturated water flow. Moreover, this process is accompanied by homogeneous generation of new nuclei to sustain their equilibrium concentration. It is shown that in an elementary cell of a crystal the energy of formation increases, whereas the probability of formation decreases in the following succession: vaterite, aragonite, and calcite. However, due to the metastability of the vaterite, the prevailing suspension on a solution turns to be consisting of aragonite crystals that have a smaller surface of the crystalline cell and a higher density than calcite. This supplements the earlier proposed model and explains the well-known experimental results.
机译:众所周知,碳酸钙CaCO3的多态性可以使晶体形成三个不同的阶段:球ate石,文石和方解石。这项工作解释了对水流磁化的一种影响,即文石纳米晶体形式的悬浮液的主要成分。根据先前基于纳米力学方法提出的模型,磁场会加速过饱和水流中纳米级临界核的凝结。而且,该过程伴随有新核的均质生成以维持其平衡浓度。结果表明,在晶体的基本晶胞中,形成能增加,而形成概率则依次减少:v石,文石和方解石。但是,由于球v石的亚稳性,溶液中的主要悬浮液由文石晶体组成,文石晶体的表面比方解石的晶体小,密度更高。这是对较早提出的模型的补充,并解释了众所周知的实验结果。

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