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Experimental Evaluation of Interfacial Free Energy of Solid Iron

机译:固态铁的界面自由能的实验评价

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摘要

Interfacial free energy of solid iron was experimentally evaluated for solid/liquid interface and grain boundary of austenite phase in solid Fe/liquid FeO-SiO_2 system. Multi-phase equilibrium method was adopted and two kinds of angles such as dihedral angle between solid/liquid interface and grain boundary, and contact angle of sessile drop of molten oxide on solid iron were measured. On the basis of experimental results and literature data of activity of FeO, surface tension of liquid FeO-SiO_2 oxide and solid Fe, interfacial tension (interfacial free energy) of solid/liquid interface and grain boundary of γ-Fe were evaluated. Oxygen partial pressure in the experimental atmosphere was evaluated as 1 × 10~(-12)~10~(-11)atm. Under this condition, solid/liquid interfacial free energy was evaluated as 1 440-1 500 mJ/m~2 and grain boundary free energy of γ-Fe as 860-940 mJ/m~2 at 1 350℃. The evaluated value for the grain boundary was agreed well with the data of previous works.
机译:实验研究了固体铁/液体FeO-SiO_2体系中固铁的界面自由能对奥氏体相的固/液界面和晶界的影响。采用多相平衡法,测量了固液界面与晶界之间的二面角,熔融氧化物在固体铁上的固着液滴的接触角等两种角度。根据实验结果和FeO活性的文献资料,对液态FeO-SiO_2氧化物和固态Fe的表面张力,固液界面的界面张力(界面自由能)和γ-Fe的晶界进行了评价。实验气氛中的氧分压为1×10〜(-12)〜10〜(-11)atm。在此条件下,在1350℃下,固液界面自由能为1440-1500mJ / m〜2,γ-Fe晶界自由能为860-940mJ / m〜2。晶界的评估值与先前的工作数据非常吻合。

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