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Reduction Behavior of Carbon Composite Pellets Including Alumina and Silica at 1 273 K and 1 373 K

机译:碳复合颗粒(包括氧化铝和二氧化硅)在1 273 K和1 373 K下的还原行为

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摘要

The effect of alumina and silica on the reaction behavior of carbon composite pellet was investigated by thermogravimetric analysis at 1 273 K (1 000℃) and 1 373 K (1 100℃). X-ray diffraction was used for the phase analysis of iron oxide changing from hematite to reduced iron. The overall reaction was divided into three stages according to phase transformation of iron oxide. CO and CO_2 from off-gas data was used for kinetic analysis and for understanding reaction mechanism. The Boudouard reaction was largely influenced by alumina and silica that changed CO gas concentration resulting in different reduction behavior of the pellets. Alumina increased the reaction rate of carbon composite pellet while silica decreased the overall reaction rate.
机译:通过在1 273 K(1000℃)和1 373 K(1100℃)下进行热重分析,研究了氧化铝和二氧化硅对碳复合材料粒料反应行为的影响。 X射线衍射用于分析从赤铁矿到还原铁的氧化铁的相分析。根据氧化铁的相变,将整个反应分为三个阶段。来自尾气数据的CO和CO_2用于动力学分析和理解反应机理。 Boudouard反应在很大程度上受到氧化铝和二氧化硅的影响,氧化铝和二氧化硅改变了CO气体的浓度,从而导致颗粒的还原行为不同。氧化铝提高了碳复合颗粒的反应速率,而二氧化硅降低了整体反应速率。

著录项

  • 来源
    《ISIJ international》 |2014年第6期|1256-1265|共10页
  • 作者

    Hyunsik PARK; Veena SAHAJWALLA;

  • 作者单位

    Centre for Sustainable Materials Research & Technology (SMaRT), School of Materials Science & Engineering, UNSW, SYDNEY, 2052 NSW, Australia;

    Centre for Sustainable Materials Research & Technology (SMaRT), School of Materials Science & Engineering, UNSW, SYDNEY, 2052 NSW, Australia;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    iron making; carbon composite pellet; reduction behavior; Boudouard reaction; alumina and silica;

    机译:炼铁碳复合颗粒减少行为;Boudouard反应;氧化铝和二氧化硅;

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