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Properties of spray-deposited liquid-phase exfoliated graphene films

机译:喷雾沉积液相剥离石墨烯薄膜的性能

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摘要

In this study, we demonstrate the feasibility of spray-depositing exfoliated graphene on flexible polyimide (PI) and rigid (soda lime glass) substrates for optoelectronic applications. The water contact angles of the substrates increased by 13% (for PI) and 49% (for glass) when the surfaces are pretreated with hexamethyldisiloxane, which significantly improved the adhesion of the films. Raman spectral analyses confirmed a minimum of 15 and a maximum of 23 layers of exfoliated graphene deposited on the substrates. After deposition, the films were exposed to 13.56 MHz radio-frequency plasma containing an admixture of argon and nitrogen gases. Plasma treatment modified the electrical properties with a response analogous to that of a rectifier. A 39% increase in transmittance in the visible region was also observed especially for glass substrates after plasma treatment without a significant change in film electrical conductivity. (C) 2018 The Japan Society of Applied Physics
机译:在这项研究中,我们证明了将剥落的石墨烯喷涂沉积在柔性聚酰亚胺(PI)和刚性(苏打石灰玻璃)基板上的可行性,以用于光电应用。当表面用六甲基二硅氧烷预处理时,基板的水接触角分别增加了13%(对于PI)和49%(对于玻璃),这大大改善了薄膜的附着力。拉曼光谱分析证实了沉积在基底上的最少15层和最多23层脱落的石墨烯。沉积之后,将膜暴露于13.56 MHz射频等离子体中,该等离子体包含氩气和氮气的混合物。等离子体处理通过类似于整流器的响应来改变电性能。还观察到在可见光区域的透射率增加了39%,尤其是对于等离子处理后的玻璃基板而言,薄膜电导率没有明显变化。 (C)2018日本应用物理学会

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