首页> 外文期刊>Japanese Journal of Applied Physics. Part 1, Regular Papers, Brief Communications & Review Papers >Control of Preferential Orientation of Platinum Films on RuO_2/SiO_2/Si Substrates by Sputtering
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Control of Preferential Orientation of Platinum Films on RuO_2/SiO_2/Si Substrates by Sputtering

机译:溅射控制RuO_2 / SiO_2 / Si衬底上铂薄膜的择优取向。

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We investigated the preferential orientation of Pt films deposited on RuO_2/SiO_2/Si substrates at a substrate temperature of 100℃ by RF magnetron sputtering, using only Ar gas without O_2 gas. It was found that, for a sputtering power less than 30 W and a sputtering gas pressure of 10 Pa, the Pt(100)-oriented volume ratio over the whole Pt film rapidly increases with film thickness. However, for a sputtering power more than 50 W and the same pressure, the ratio slightly increases with thickness, and it is suppressed by increasing the power. On the other hand, the Pt(111)-oriented volume ratio is smaller and decreases with thickness irrespective of the power, whereas it is increased by decreasing the pressure to 4 Pa at 20 W. From these results, it can be considered that (111)-oriented crystalline growth is mainly driven by the lowest surface energy and that (100)-oriented growth is mainly driven by the strain energy due to intrinsic tensile stress which is increased with thickness and pressure, and decreased with power.
机译:我们研究了通过RF磁控溅射在RuO_2 / SiO_2 / Si衬底上沉积的Pt膜在100℃衬底温度下的优先取向,仅使用Ar气体而不使用O_2气体。已经发现,对于小于30W的溅射功率和10Pa的溅射气压,在整个Pt膜上的Pt(100)取向的体积比随着膜厚度而迅速增加。然而,对于大于50W且相同压力的溅射功率,该比率随厚度而略微增加,并且通过增加功率来抑制。另一方面,Pt(111)取向的体积比较小,并且与厚度无关,与功率无关,而通过在20 W时将压力降低至4 Pa可以增加。从这些结果可以认为( 111)取向的晶体生长主要由最低的表面能驱动,而(100)取向的生长主要由应变能驱动,这是由于固有拉伸应力引起的,该拉伸应力随厚度和压力的增加而随功率的降低而减小。

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