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Effect of H_2 Addition during Cu Thin-Film Sputtering

机译:铜薄膜溅射过程中H_2添加的影响

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摘要

We have investigated the effect of H_2 addition during Cu sputtering. It was found that the Cu surface becomes smooth with increasing amount of H_2 added to Ar plasma during Cu sputtering. The arithmetical mean roughness decreases by 40% with H_2 (60%) addition. The X-ray diffraction peak intensity ratio [Cu(111)/Cu(200)] increases with H_2 content, which indicates that the crystallinity of the Cu film has been improved. The property of Cu filling in the contact hole is much improved by H_2 addition sputtering after low-temperature annealing (350 ℃). Cu film was electroplated on the sputtered Cu. The roughness of the electroplated Cu surface does not depend on the roughness of the initial sputtered Cu surface even though H_2 is added during Cu sputtering. However, the crystal orientation of the electroplated Cu film [(111)/(200) ratio] can be controlled by the crystal orientation of the seed sputtered Cu film; that is, H_2 addition during Cu sputtering results in a good crystal orientation of the electroplated Cu film.
机译:我们研究了铜溅射过程中添加H_2的影响。发现在Cu溅射期间,随着添加到Ar等离子体中的H_2的量增加,Cu表面变得光滑。加入H_2(60%)后,算术平均粗糙度降低40%。 X射线衍射峰强度比[Cu(111)/ Cu(200)]随着H_2含量的增加而增加,这表明Cu膜的结晶度得到了改善。低温退火(350℃)后通过H_2附加溅射大大提高了接触孔中Cu的填充性能。将铜膜电镀在溅射的铜上。即使在Cu溅射过程中添加了H_2,电镀Cu表面的粗糙度也不取决于初始溅射的Cu表面的粗糙度。但是,可以通过晶种溅射的Cu膜的晶体取向来控制电镀Cu膜的晶体取向[(111)/(200)比]。即,通过在Cu溅射中添加H_2,可以使电镀Cu膜的晶体取向性良好。

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