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首页> 外文期刊>Japanese Journal of Applied Physics. Part 1, Regular Papers & Short Notes >Effect of B_2O_3 and CuO on the Sintering Temperature and Microwave Dielectric Properties of Ba(Zn_(1/3)Ta_(2/3_)O_3 Ceramics
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Effect of B_2O_3 and CuO on the Sintering Temperature and Microwave Dielectric Properties of Ba(Zn_(1/3)Ta_(2/3_)O_3 Ceramics

机译:B_2O_3和CuO对Ba(Zn_(1/3)Ta_(2 / 3_)O_3陶瓷的烧结温度和微波介电性能的影响

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Sintering temperature of the Ba(Zn_(1/3)Ta_(2/3_)O_3 (BZT) ceramic is about 1550℃ and it decreased to 950℃ when B_2O_3 was added. The BaB_4O_7 second phase whose melting temperature is 889℃ was found in the B_2O_3 added BZT ceramics. The BaB_4O_7 second phase assisted the sintering of the BZT ceramics at 950℃. However, the B_2O_3 added BZT ceramic was not sintered below 950℃ and the microwave dielecric properties were not satisfactory. On the other hand, when the B_2O_3 and the CuO were added, the BZT ceramic was sintered even at 870℃. The BaCu(B_2O_5) phase which was found in the CuO and B_2O_3 added BZT ceramics, existed as the liquid phase during the sintering and helped the densification of the BZT ceramics at temperatures lower than 950℃. Good microwave dielectric properties of Q x f = 11,000 GHz, ε_r = 26 and τ_f = 0.0 ppm/℃ were obtained from the BZT + 5.0 mol% B_2O_3 + 10.0 mol% CuO ceramic sintered at 870℃ for 2h.
机译:Ba(Zn_(1/3)Ta_(2 / 3_)O_3(BZT)陶瓷的烧结温度约为1550℃,加入B_2O_3时烧结温度降至950℃,发现BaB_4O_7第二相的熔化温度为889℃。在B_2O_3中添加BZT陶瓷时,BaB_4O_7第二相辅助了950℃时的BZT陶瓷的烧结,但是在950℃以下时,B_2O_3中添加的BZT陶瓷没有被烧结,微波介电性能不令人满意。加入B_2O_3和CuO后,即使在870℃烧结BZT陶瓷,在CuO和B_2O_3中添加的BZT陶瓷中发现的BaCu(B_2O_5)相在烧结过程中以液相形式存在,有助于陶瓷的致密化。 BZT陶瓷在低于950℃的温度下,由BZT + 5.0 mol%B_2O_3 + 10.0 mol%CuO陶瓷在870℃烧结得到Q Qf = 11,000 GHz,ε_r= 26和τ_f= 0.0 ppm /℃的良好微波介电性能2小时。

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