4-Phenyloxazolidin-2-ones and isoindolin-1-ones: chiral auxiliaries for Diels–Alder reactions of N-substituted 1,3-dienes

Helena McAlonan James P. Murphy Mark Nieuwenhuyzen Karen Reynolds Pakala K. S. Sarma Paul J. Stevenson and Norris Thompson

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4-Phenyloxazolidin-2-ones and isoindolin-1-ones: chiral auxiliaries for Diels–Alder reactions of N-substituted 1,3-dienes

机译：4-苯恶唑烷-2-酮和异吲哚-1-酮：手性助剂，用于N-取代的1,3-二烯的狄尔斯-阿尔德反应

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Terminally N-substituted dienes derived from 3-methylisoindolin-1-one, 4-isopropyl- and 4-phenyloxazolidin-2-onenundergo Diels–Alder reaction with a range of activated dienophiles. The reactions reported are completely regio- andnendo-selective, with the diastereoisomeric excess with respect to the auxiliary good to excellent in most of the casesnreported. A model has been developed for rationalising the stereochemical outcome of these reactions.

机译：末端N取代的二烯衍生自3-甲基异吲哚啉-1-酮，4-异丙基-和4-苯基恶唑烷丁-2-烯酮，通过Diels-Alder反应与一系列活化的亲二烯体反应。报道的反应是完全区域和烯醇选择性的，在大多数情况下，相对于助剂而言，非对映异构体过量至优异。已经开发了用于合理化这些反应的立体化学结果的模型。

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《Journal of the Chemical Society, Perkin Transactions 1》 |2002年第1期|p.69-79|共11页
作者
Helena McAlonan James P. Murphy Mark Nieuwenhuyzen Karen Reynolds Pakala K. S. Sarma Paul J. Stevenson and Norris Thompson;
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School of Chemistry, The Queen’s University of Belfast, Belfast, Northern Ireland,UK BT9 5AG;

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1. 4-Phenyloxazolidin-2-ones and isoindolin-1-ones: chiral auxiliaries for Diels-Alder reactions of N-substituted 1,3-dienes [J] . McAlonan H., Murphy JP., Nieuwenhuyzen M., Journal of the Chemical Society, Perkin Transactions 1 . 2002,第1期

机译：4-苯恶唑烷-2-酮和异吲哚-1-酮：N取代1,3-二烯Diels-Alder反应的手性助剂
2. Facial selectivity in the Diels-Alder reactions of 2,2-disubstituted cyclopent-4-ene-1,3-dione derivatives and a computational examination of the facial selectivity of the Diels-Alder reactions of structurally related dienes and dienophiles [J] . Liu P.-Y., Wu Y.-J., Pye C.C., European journal of organic chemistry . 2012,第6期

机译：2,2-二取代的环戊-4-烯-1,3-二酮衍生物的Diels-Alder反应中的面部选择性以及结构相关二烯和亲二烯体的Diels-Alder反应的面部选择性的计算研究
3. Highly Enaetioselective Hetero-Diels-Alder Reaction of 1,3-Bis-(silyloxy)-1,3-dienes with Aldehydes Catalyzed by Chiral Disulfonimide [J] . Joyram Guin, Constantinos Rabalakos, Benjamin List Angewandte Chemie . 2012,第35期

机译：手性二磺酰亚胺催化的1,3-双-（甲硅烷氧基）-1,3-二烯与醛的高度对映体杂Diels-Alder反应
4. A Highly Enantioselective Hetero-Diels-Alder Reaction of Aldehydes withDanishefsky's Diene Catalyed by Chiral Titanium (Ⅳ) H8-Binolcomplexes [C] . (missing) International symposium on green chemistry in China . 2002

机译：一种高度映选择性的异源二氧化醛醛与手性钛（Ⅵ）H8-Binolcomplecces的醛催化的醛催化反应
5. Synthesis of 2-boron substituted-1,3-dienes and their Diels-Alder/Suzuki cross coupling reactions. [D] . Wang, Liqiong. 2012

机译：2-硼取代的1,3-二烯的合成及其Diels-Alder / Suzuki交叉偶联反应。
6. Asymmetric aza-Diels-Alder reaction of Danishefskys diene with imines in a chiral reaction medium [O] . Bruce Pégot, Olivier Nguyen Van Buu, Didier Gori, 2006

机译：手性反应介质中丹尼舍夫斯基二烯与亚胺的不对称aza-Diels-Alder反应
7. New Synthesis and Diels–Alder Reactions of 2-Aminomethyl-1,3-butadienes and Related 1,3-Dienes [O] . Akira Hosomi, Toshiyuki Masunari, Yoshinori Tominaga, 1991

机译：2-氨基甲基-1,3-丁二烯和相关1,3-二烯的新合成和Diels-Alder反应
8. Diels-Alder Reactions of a Surfactant 1,3-Diene [R] . Jaeger, D. A., Shinozaki, H., Goodson, P. A. 1991

机译：表面活性剂1,3-二烯的Diels-alder反应

4-Phenyloxazolidin-2-ones and isoindolin-1-ones: chiral auxiliaries for Diels–Alder reactions of N-substituted 1,3-dienes

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