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首页> 外文期刊>Journal of the American Ceramic Society >Normal-Relaxor-Diffuse Ferroelectric Phase Transition and Electrical Properties of Bi(Mg_(1/2)Ti_(1/2))_3-PbZrO_3-PbTiO_3 Solid Solution Ceramics Near the Morphotropic Phase Boundary
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Normal-Relaxor-Diffuse Ferroelectric Phase Transition and Electrical Properties of Bi(Mg_(1/2)Ti_(1/2))_3-PbZrO_3-PbTiO_3 Solid Solution Ceramics Near the Morphotropic Phase Boundary

机译:Bi(Mg_(1/2)Ti_(1/2))_ 3-PbZrO_3-PbTiO_3固溶陶瓷在正向相界附近的正相-扩散铁电相变和电性能

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摘要

Perovskite-type xBi(Mg_(1/2)Ti_(1/2))O_3-(0.56 - x)PbZrO_3-0.44 PbTiO_3 (xBMT-PZ-PT) ternary solid solution ceramics were synthesized via a conventional solid-state reaction method. The phase transition behaviors, dielectric, ferroelectric, and piezoelectric properties were investigated as a function of the BMT content. The X-ray diffraction analysis showed that the tetrag-onality of xBMT-PZ-PT was enhanced with increasing the BMT content, and a morphotropic phase boundary (MPB) between rhombohedral and tetragonal phases was identified approximately in the composition of x = 0.08. In addition, the dielectric diffuseness and frequency dispersion behavior were induced with the addition of BMT and a normal-relaxor-diffuse ferroelectric transformation was observed from the PZ-rich side to the BMT-rich side. The electrical properties of xBMT-PZ-PT ceramics exhibit obviously compositional dependence. The x = 0.08 composition not only possessed the optimum properties with ε~t_(33)/ε_0 = 1450, Q_m = 69, d_(33) = 390 pC/N, k_p = 0.46, P_r = 30 μC/cm~2, E_c = 1.4 kV/mm, T_c = 325℃, and a strain of 0.174% (d_(33)~* = 436 pm/V) under an electric field of 4 kV/mm as a result of the coexistence of two ferroelectric phases near the MPB, but also owned a good thermal-depolarization behavior with a d_(33) value of >315 pC/N up to 290℃ and a frequency-insensitive strain behavior.
机译:钙钛矿型xBi(Mg_(1/2)Ti_(1/2))O_3-(0.56-x)PbZrO_3-0.44 PbTiO_3(xBMT-PZ-PT)三元固溶陶瓷是通过常规固相反应方法合成的。研究了相变行为,介电,铁电和压电特性随BMT含量的变化。 X射线衍射分析表明,随着BMT含量的增加,xBMT-PZ-PT的四重性增强,并且在x = 0.08的成分中,菱形和四方相之间的相变相界(MPB)被确定。另外,通过添加BMT引起介电扩散和频率色散行为,并且从富PZ侧到富BMT侧观察到正常的弛豫-扩散铁电转变。 xBMT-PZ-PT陶瓷的电性能表现出明显的成分依赖性。 x = 0.08的成分不仅具有ε〜t_(33)/ε_0= 1450,Q_m = 69,d_(33)= 390 pC / N,k_p = 0.46,P_r = 30μC/ cm〜2, E_c = 1.4 kV / mm,T_c = 325℃,并且由于两个铁电相共存,在4 kV / mm的电场下应变为0.174%(d_(33)〜* = 436 pm / V)在MPB附近,还具有良好的热去极化行为,在290℃时d_(33)值> 315 pC / N,并且对频率不敏感。

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  • 来源
    《Journal of the American Ceramic Society》 |2014年第6期|1912-1917|共6页
  • 作者

    Haifeng Yi; Ruzhong Zuo;

  • 作者单位

    Institute of Electro Ceramics & Devices, School of Materials Science and Engineering, Hefei University of Technology,Hefei 230009, China;

    Institute of Electro Ceramics & Devices, School of Materials Science and Engineering, Hefei University of Technology,Hefei 230009, China;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);
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  • 正文语种 eng
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