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Temporal determination of heavy metals in PM_(2.5) aerosols in a suburban site of Athens, Greece

机译:时间测定希腊雅典郊区PM_(2.5)气溶胶中的重金属

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摘要

Twenty-three hours samples of airborne aerosols PM_(2.5) were collected during summer (August-September) and winter (October-November) 2003 in a suburban area of Athens (Aghia Paraskevi), Greece. The objective of this study is the determination of heavy metals (Hg, Cd, Ni, Pb, As) concentration in PM_(2.5). In particular, the mean daily concentrations of the five detected metals are compared to the limit values established by the E.U (Directive 96/62/E.U.) and correlated with the mean daily concentrations of PM_(2.5) as well as with meteorological parameters. Finally, the present work examines the daily levels of fine particles in comparison with the proposed limit values from the U.S. Environmental Pollution Agency (65 μg/m~3) and investigates their interaction with other inorganic air pollutants. The concentrations of PM_(2.5) as well as the concentrations of the five heavy metals proved to be lower than the limit values. Additionally fine particles proved to be strongly influenced by the photochemical processes that take place during the hot days of the year. As far as the heavy metals are concerned, only Cd and Pb seem to be slightly correlated.
机译:在希腊雅典郊区(Aghia Paraskevi),于2003年夏季(8月至9月)和冬季(10月至11月)收集了23个小时的气溶胶PM_(2.5)样品。这项研究的目的是测定PM_(2.5)中重金属(Hg,Cd,Ni,Pb,As)的浓度。特别是,将五种检测到的金属的日平均浓度与E.U(指令96/62 / E.U。)确定的极限值进行比较,并将其与PM_(2.5)的日平均浓度以及气象参数相关联。最后,目前的工作是与美国环境污染管理局(65μg/ m〜3)提出的限值相比较,检查每日的细颗粒水平,并研究它们与其他无机空气污染物的相互作用。事实证明,PM_(2.5)的浓度以及五种重金属的浓度均低于极限值。此外,细颗粒物还受到一年中炎热季节发生的光化学过程的强烈影响。就重金属而言,似乎只有Cd和Pb略有相关。

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