Synthesis and Structure of Compound Bis-benzylamino-silver(I) Benzylcarbamate

Yu Cao; Jian-Guo Liu; Xiang-You Li; Xiao-Yan Zeng; Hua Li

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Synthesis and Structure of Compound Bis-benzylamino-silver(I) Benzylcarbamate

机译：化合物双苄氨基银（I）苄基氨基甲酸酯的合成与结构

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摘要

A novel silver-containing compound bis-benzylamino-silver(I) benzylcarbamate with the molecular formula of C22H26N3O2Ag and structural formula of C6H5CH2NHCOOAg(NH2CH2C6H5)2 is synthesized by the reaction of benzylamonium benzylcarbamate and silver oxide. It crystallizes in triclinic crystal system and P-1 space group with a = 5.2006(5) Å, b = 14.6298(15) Å, c = 14.7246(15) Å, α = 68.729(2)°, β = 83.507(2)°, γ = 85.412(2)°, and Z = 2. In the crystal, all of the silver atoms are two-coordinate, i.e., one silver atom symmetrically chelates with the two amino groups in two benzylamine molecules, while all the carboxylate groups only act as charge balancers. In addition, the crystal contains a large quantity of hydrogen bonds sustaining the stability of three-dimensional structure.

机译：一种新型的含银化合物C22 H26 N3 O2 Ag的分子式和C6 的结构式H5 CH2 NHCOOAg（NH2 CH2 C6 H5 ）2 是由苄基氨基甲酸苄基铵与氧化银反应合成的。它在三斜晶系和P-1空间群中结晶，a = 5.2006（5）Å，b = 14.6298（15）Å，c = 14.7246（15）Å，α= 68.729（2）°，β= 83.507（2 ）°，γ= 85.412（2）°，Z =2。在晶体中，所有银原子均为两个配位，即一个银原子与两个苄胺分子中的两个氨基对称地螯合，而所有羧酸酯基仅充当电荷平衡剂。另外，该晶体包含大量维持三维结构稳定性的氢键。

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来源
《Journal of Chemical Crystallography》 |2012年第8期|p.891-896|共6页
作者
Yu Cao; Jian-Guo Liu; Xiang-You Li; Xiao-Yan Zeng; Hua Li;
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作者单位

College of Mechanical &amp Electrical Engineering, Wenzhou University, Wenzhou, 325000, People’s Republic of China;

Wuhan National Laboratory for Optoelectronics, College of Optoelectronics Science and Engineering, Huazhong University of Science and Technology, Wuhan, 430074, People’s Republic of China;

Wuhan National Laboratory for Optoelectronics, College of Optoelectronics Science and Engineering, Huazhong University of Science and Technology, Wuhan, 430074, People’s Republic of China;

Wuhan National Laboratory for Optoelectronics, College of Optoelectronics Science and Engineering, Huazhong University of Science and Technology, Wuhan, 430074, People’s Republic of China;

College of Chemistry and Molecular Science, Wuhan University, Wuhan, 430072, People’s Republic of China;

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正文语种 eng
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关键词
Silver metal–organic compound; Bis-benzylamino-silver(I) benzylcarbamate; Two-coordinate molecular structure;

机译：银-有机化合物;双-苄氨基银-氨基甲酸银（I）;二配位分子结构;

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Synthesis and Structure of Compound Bis-benzylamino-silver(I) Benzylcarbamate

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