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首页> 外文期刊>Journal of Crystal Growth >Epitaxial CaGe_2 films on germanium
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Epitaxial CaGe_2 films on germanium

机译:锗上的外延CaGe_2薄膜

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摘要

The epitaxial growth of thin CaGe_2 films with reactive deposition epitaxy (RDE) on Ge(111) substrates is described. The films consist in general of a mixture of the known trigonal rhombohedral tr6 modification and a hexagonal h2 modification of CaGe_2 containing two Ca and two buckled Ge layers per unit cell in a twofold stacking sequence whose formation appears to be favored by strain. Epitaxial layers of both polytypes show remarkably higher crystalline quality compared to epitaxial CaSi_2 films grown on silicon substrates. The tr6 modification is found to be unstable in air in contrast to the h2 modification.
机译:描述了在Ge(111)衬底上外延生长具有反应性沉积外延(RDE)的CaGe_2薄膜的过程。膜通常由已知的三角形菱面体tr6修饰和六面体h2修饰的CaGe_2的混合物组成,CaGe_2每单位晶胞按两倍堆叠顺序包含两个Ca和两个弯曲的Ge层,其形成似乎受应变的影响。与在硅衬底上生长的外延CaSi_2膜相比,两种多型的外延层均显示出明显更高的结晶质量。与h2修饰相反,发现tr6修饰在空气中不稳定。

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