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首页> 外文期刊>Journal of Crystal Growth >Model of polyassosiative solutions and its application for the analysis of p-T-x equilibrium in iron-like oxide solutions and A~2B~6 semiconductor systems
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Model of polyassosiative solutions and its application for the analysis of p-T-x equilibrium in iron-like oxide solutions and A~2B~6 semiconductor systems

机译:聚缔合溶液模型及其在类铁氧化物溶液和A〜2B〜6半导体系统中p-T-x平衡分析中的应用

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This work is the analysis of phase equilibria using the thermodynamic model of solutions, in which it is assumed that the strong interaction between the liquid phase components is due to the presence of atomic complexes of different compositions (polyassociative solutions model-PAS model). It is an analysis of its effectiveness and validity when creating p-T-x phase diagrams for A~2B~6 semiconductor compounds, as well as for magnetic oxide solid solutions crystallizing to a spinel structure. The theoretical analysis results were compared with the experimental ones. Conclusions were drawn regarding the effectiveness of the PAS model, application restrictions were discussed, and long-term perspective application directions in the analysis of phase equilibrium were identified.
机译:这项工作是使用溶液的热力学模型对相平衡进行分析,其中假设液相组分之间的强相互作用是由于存在不同组成的原子络合物(多缔合溶液模型-PAS模型)。它是为A〜2B〜6半导体化合物以及结晶为尖晶石结构的磁性氧化物固溶体创建p-T-x相图时对其有效性和有效性的分析。将理论分析结果与实验结果进行了比较。得出有关PAS模型有效性的结论,讨论了应用限制,并确定了相平衡分析中的长期应用前景。

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