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首页> 外文期刊>Journal of Crystal Growth >Atomic force microscopy study on crystal growth of Cu (2+)-doped L-arginine phosphate monohydrate crystals
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Atomic force microscopy study on crystal growth of Cu (2+)-doped L-arginine phosphate monohydrate crystals

机译:掺杂铜(2+)的L-精氨酸磷酸一水合物晶体生长的原子力显微镜研究

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摘要

Sub-steps and defects of the {100} planes of Cu2+-doped L-arginine phosphate monohydrate (LAP) crystals are observed by atomic force microscopy. Formation of sub-steps is not due to the stacking faults but a result of single LAP: Cu2+ molecule acting as growth unit. Two-dimensional (2D) nuclei with the same height as sub-steps occur on the step-edges. Impurities of Cu2+ ions cause steps bunch and macrosteps formation. Liquid inclusions in the form of long channels form when the macrosteps lose their stability. Numerous small 3D growth hillocks are found in the channels. The extra stress induced by the 3D islands can result in dislocations and steps mismatches. (C) 2004 Elsevier B.V. All rights reserved.
机译:原子力显微镜观察到了掺杂Cu2 +的L-精氨酸磷酸一水合物(LAP)晶体的{100}平面的子步骤和缺陷。子步骤的形成不是由于堆垛层错,而是单个LAP:Cu2 +分子充当生长单元的结果。与子步高度相同的二维(2D)原子核出现在台阶边缘。 Cu2 +离子的杂质会导致台阶堆积和大台阶形成。当宏观台阶失去稳定性时,会形成长通道形式的液体夹杂物。在通道中发现了许多小型3D增长岗。由3D岛引起的额外应力可能导致位错和台阶不匹配。 (C)2004 Elsevier B.V.保留所有权利。

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