...
首页> 外文期刊>Journal of Crystal Growth >Electron beam induced deposition of rhodium from the precursor [RhCl(PF_3)_2]_2: morphology, structure and chemical composition
【24h】

Electron beam induced deposition of rhodium from the precursor [RhCl(PF_3)_2]_2: morphology, structure and chemical composition

机译:电子束诱导的铑从前体[RhCl(PF_3)_2] _2的沉积:形貌,结构和化学组成

获取原文
获取原文并翻译 | 示例
           

摘要

We have studied the morphology, the structure and the chemical composition of micro- and nano-structures grown by electron beam-induced deposition of [RhCl(PF_3)_2]_2. Transmission electron microscopy revealed that the deposits are made up of face centered cubic crystalline Rh grains (4-6 nm in diameter) immersed in an amorphous matrix. Auger electron spectroscopy and electron energy loss spectroscopy showed that a carbon contamination layer is present at the deposit surface, while the bulk material contains the elements Rh (60 at%), P (20 at%), Cl, O and N (remaining 20 at%). The structure, the chemical composition of the deposits and the size of the Rh nano-crystals are independent of the deposit shape and of the deposition parameters, within the range explored in this work.
机译:我们研究了通过电子束诱导的[RhCl(PF_3)_2] _2沉积而形成的微结构和纳米结构的形态,结构和化学组成。透射电子显微镜显示,沉积物由浸没在非晶基质中的面心立方晶体Rh晶粒(直径4-6 nm)组成。俄歇电子能谱和电子能量损失能谱表明,沉积物表面存在碳污染层,而块状材料则包含元素Rh(60 at%),P(20 at%),Cl,O和N(剩余20)。在%)。在这项工作探索的范围内,沉积物的结构,化学成分和Rh纳米晶体的大小与沉积物的形状和沉积参数无关。

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱:kefu@zhangqiaokeyan.com

京公网安备:11010802029741号 ICP备案号:京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有
  • 客服微信

  • 服务号