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首页> 外文期刊>Journal of Crystal Growth >Influence of lattice polarity on wurzite GaN{0001} decomposition as studied by in situ gravimetric monitoring method
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Influence of lattice polarity on wurzite GaN{0001} decomposition as studied by in situ gravimetric monitoring method

机译:原位重量监测法研究晶格极性对纤锌矿GaN {0001}分解的影响

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摘要

The influence of lattice polarity on wurzite GaN{0001} decomposition was investigated using an in situ gravimetric monitoring (GM) method with freestanding GaN(0001). At temperatures below about 820 deg C, the decomposition rate of GaN(0001) was faster than that of GaN(0001). On the other hand, the decomposition rate of GaN(0001) was faster than that of GaN(0001) at temperatures between about 850 deg C and 950 deg C. The relation between the decomposition rate and the H2 partial pressure (PH2) indicates that the rate-limiting reactions are N(surface)+ 1/2 H_2(g)-NH_3(g) at lower temperatures, but Ga(surface)+3/2 H_2(g)-- GaH(g) at higher temperatures.
机译:使用具有独立式GaN(0001)的原位重量监测(GM)方法研究了晶格极性对纤锌矿GaN {0001}分解的影响。在低于约820℃的温度下,GaN(0001)的分解速率比GaN(0001)的分解速率快。另一方面,在约850℃至950℃之间的温度下,GaN(0001)的分解速率比GaN(0001)快。分解速率与H2分压(PH2)之间的关系表明:限速反应在较低温度下为N(表面)+ 1/2 H_2(g)-NH_3(g),而在较高温度下为Ga(表面)+3/2 H_2(g)-GaH(g)。

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