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Emissions of polychlorinated diphenyl ethers from a municipal solid waste incinerator during the start-up operation

机译:在启动过程中,市政垃圾焚烧炉排放的多氯二苯醚

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摘要

This study examines the emissions of polychlorinated diphenyl ethers (PCDEs) during the start-up processes of a municipal solid waste incinerator (MSWI). Both normal and modified emission control start-ups were tested. Fifteen samples were taken from the flue gas with increasing furnace temperature. Peak PCDE concentrations of 1.48-10.3 ng/Nm(3) were observed at 8-11 h after the start of combustion, when the furnace temperature was in the range of 267-440 degrees C, that also needed for PCDD/F formation by de novo synthesis. The PCDE emissions could thus, be reduced by current control techniques. Furthermore, the modified control strategies inhibited PCDE formation at the beginning of combustion, and led to an 86% reduction in the maximum PCDE concentration. The overall start-up emissions were calculated as 1.01-3.08 mg, while the annual PCDE emissions with one start-up operation were found to be 7.48-9.64 mg. However, total PCDE emissions will increase by 12-69% if the number of start-up runs increases to between two and eight times per year. Consequently, the prevention of the unnecessary start-ups and advanced activation of the related emission control system are both efficient ways to reduce PCDE emissions. (C) 2015 Elsevier B.V. All rights reserved.
机译:这项研究检查了市政固体废物焚化炉(MSWI)启动过程中多氯二苯醚(PCDE)的排放。测试了正常和改进的排放控制启动装置。随着炉温的升高,从烟气中抽取了15个样品。在燃烧开始后的8-11小时内观察到PCDE的峰值浓度为1.48-10.3 ng / Nm(3),当炉温在267-440摄氏度范围内时,PCDD / F的形成也需要从头合成。因此,可以通过当前的控制技术来减少PCDE的排放。此外,改进的控制策略在燃烧开始时抑制了PCDE的形成,并使最大PCDE浓度降低了86%。计算出的总启动排放量为1.01-3.08 mg,而一次启动运行的年PCDE排放量为7.48-9.64 mg。但是,如果启动运行次数每年增加两次至八次,则PCDE的总排放量将增加12-69%。因此,防止不必要的启动和相关排放控制系统的高级激活都是减少PCDE排放的有效方法。 (C)2015 Elsevier B.V.保留所有权利。

著录项

  • 来源
    《Journal of Hazardous Materials》 |2015年第15期|206-214|共9页
  • 作者单位

    Natl Cheng Kung Univ, Dept Environm Engn, Tainan 70101, Taiwan;

    Cheng Shiu Univ, Dept Civil Engn & Geomat, Kaohsiung 83347, Taiwan|Cheng Shiu Univ, Super Micro Mass Res & Technol Ctr, Kaohsiung 83347, Taiwan;

    Natl Cheng Kung Univ, Dept Environm Engn, Tainan 70101, Taiwan;

    Natl Cheng Kung Univ, Dept Environm Engn, Tainan 70101, Taiwan;

    Cheng Shiu Univ, Dept Civil Engn & Geomat, Kaohsiung 83347, Taiwan;

    Cheng Shiu Univ, Super Micro Mass Res & Technol Ctr, Kaohsiung 83347, Taiwan|Dept Cosmet & Fash Styling, Kaohsiung 83347, Taiwan;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);美国《化学文摘》(CA);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    Polychlorinated diphenyl ether; Municipal solid waste incinerator; Start-up; Emission control; Annual emission;

    机译:多氯联苯醚;城市固体废物焚烧炉;启动;排放控制;年排放量;

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