CRYSTAL AND MOLECULAR STRUCTURE OF BIS(ETA(5)-METHYLCYCLOPENTADIENYL)TITANA(IV)-CYCLOHEXASULFANE, TI(ETA(5)-C5H4CH3)(2)S-5

Klouras N.; Terzis A.; Raptopoulou CP.; Demakopoulos I.

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CRYSTAL AND MOLECULAR STRUCTURE OF BIS(ETA(5)-METHYLCYCLOPENTADIENYL)TITANA(IV)-CYCLOHEXASULFANE, TI(ETA(5)-C5H4CH3)(2)S-5

机译：BIS（ETA（5）-甲基环戊二烯基）TITANA（IV）-环己基砜，TI（ETA（5）-C5H4CH3）（2）S-5的晶体和分子结构

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The crystal and molecular structure of Ti(eta(5)-C5H4CH3)(2)S-5 has been determined by X-ray diffraction studies. The substance crystallizes in the monoclinic crystal system [a = 6.8642(5), b = 16.507(1), c = 13.074(1) Angstrom, beta = 82.407(3)degrees, space group P2(1), Z = 4]. The geometry about the titanium atom is a distorted tetrahedron, with a (centroid)Ti-(centroid) angle of 131.29 degrees and a S-Ti-S angle of 93.38 degrees. The six-membered ring TiS5 has a cyclohexane-like chair configuration. The structural results are compared to those for similar type titanium complexes. [References: 9]

机译：Ti（eta（5）-C5H4CH3）（2）S-5的晶体和分子结构已通过X射线衍射研究确定。该物质在单斜晶体系统中结晶[a = 6.8642（5），b = 16.507（1），c = 13.074（1）埃，β= 82.407（3）度，空间群P2（1）/ n，Z = 4]。钛原子周围的几何形状是扭曲的四面体，（质心）Ti-（质心）角为131.29度，S-Ti-S角为93.38度。六元环TiS5具有类似环己烷的椅子构型。将结构结果与类似类型的钛配合物进行比较。 [参考：9]

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《Zeitschrift fur Anorganische und Allgemeine Chemie》 |1995年第1期|p. 113-116|共4页
作者
Klouras N.; Terzis A.; Raptopoulou CP.; Demakopoulos I.;
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UNIV PATRAS DEPT CHEM GR-26110 PATRAI GREECE;

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正文语种 eng
中图分类化学;
关键词
Metallacyclohexasulfanes; Titanocene pentasulfide chelates; X-ray analysis;

机译：金属环六硫烷;二茂钛五新统螯合物;X射线分析;

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1. Crystal structure of bis(eta(5)-methylcyclopentadienyl)-bis(4-methylbenzenesulfonato-O)-molybde num(IV) [J] . Balzarek C., Tyler DR., Weakley TJR. Journal of chemical crystallography . 2002,第7期

机译：双（η（5）-甲基环戊二烯基）-双（4-甲基苯磺酰基-O）-钼编号（IV）的晶体结构
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机译：钛（IV）的双（β-二酮）配合物的异构体丰度。抗肿瘤化合物布丁烷[Ti-IV（bzac）（2）（OEt）（2）]及其二氯衍生物[Ti-IV（bzac）（2）Cl-2]（bzac = 1-苯基丁烷）的晶体结构-1,3-二酸酯
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4. The Crystal Structure and Magnetic Property of Bi-substituted Nd_2Fe_(17-x-y)Ti_xSi_y Intermetallic Compounds [C] . Limei Sun, Songbai Han, Yuntao Liu, International Conference on Machine Tool Technology and Mechatronics Engineering . 2014

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CRYSTAL AND MOLECULAR STRUCTURE OF BIS(ETA(5)-METHYLCYCLOPENTADIENYL)TITANA(IV)-CYCLOHEXASULFANE, TI(ETA(5)-C5H4CH3)(2)S-5

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