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Anisotropic valence band dispersion of single crystal pentacene as measured by angle-resolved ultraviolet photoelectron spectroscopy

机译:角分辨紫外光电子能谱法测量并五苯单晶的各向异性价带色散

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摘要

Electronic structures of single crystal pentacene are of great interest for the elucidation of charge carrier transport in organic semiconductor materials. Experimental observation of valence band dispersion was recently achieved on single crystal samples of pentacene; however, its intrinsic properties are still unresolved because past experiments were performed on specimens with surface oxides formed by exposure to the ambient atmosphere. In this work, X-ray photoelectron spectroscopy (XPS) and angle-resolved ultraviolet photoelectron spectroscopy (ARUPS) were conducted on single-crystal pentacene samples prepared without ambient exposure. The XPS results confirmed the reduction of the abundance of oxide impurities on the present samples. The ARUPS measurements clearly resolved the valence band structures of the single-crystal pentacene in four symmetry directions of the surface Brillouin zone, indicating anisotropy of at least a factor of 2.4 for the intermolecular transfer integral and hole effective mass at the valence band maximum.
机译:单晶并五苯的电子结构对于阐明有机半导体材料中的载流子传输非常感兴趣。最近在并五苯单晶样品上完成了价带色散的实验观察。然而,由于过去的实验是在具有暴露于周围大气中形成的表面氧化物的样品上进行的,因此其固有性质仍未得到解决。在这项工作中,对制备的无环境暴露的单晶并五苯样品进行了X射线光电子能谱(XPS)和角分辨紫外光电子能谱(ARUPS)。 XPS结果证实了本样品中大量氧化物杂质的减少。 ARUPS测量结果清楚地分辨了单晶并五苯在表面布里渊区的四个对称方向上的价带结构,这表明在价带最大值处,分子间转移积分和空穴有效质量的各向异性至少为2.4倍。

著录项

  • 来源
    《Journal of Materials Research》 |2018年第20期|3362-3370|共9页
  • 作者单位

    Tokyo Univ Sci, Dept Pure & Appl Chem, Noda, Chiba 2788510, Japan;

    Tokyo Univ Sci, Dept Pure & Appl Chem, Noda, Chiba 2788510, Japan;

    Tokyo Univ Sci, Dept Pure & Appl Chem, Noda, Chiba 2788510, Japan;

    Natl Inst Nat Sci, Inst Mol Sci, Okazaki, Aichi 4448585, Japan|SOKENDAI, Okazaki, Aichi 4448585, Japan;

    Natl Inst Nat Sci, Inst Mol Sci, Okazaki, Aichi 4448585, Japan|SOKENDAI, Okazaki, Aichi 4448585, Japan;

    Tokyo Univ Sci, Dept Pure & Appl Chem, Noda, Chiba 2788510, Japan;

    Tokyo Univ Sci, Dept Pure & Appl Chem, Noda, Chiba 2788510, Japan;

    High Energy Accelerator Res Org KEK, Inst Mat Struct Sci, Tsukuba, Ibaraki 3050801, Japan|SOKENDAI, Tsukuba, Ibaraki 3050801, Japan;

    Natl Inst Nat Sci, Inst Mol Sci, Okazaki, Aichi 4448585, Japan|SOKENDAI, Okazaki, Aichi 4448585, Japan;

    Natl Inst Nat Sci, Inst Mol Sci, Okazaki, Aichi 4448585, Japan|SOKENDAI, Okazaki, Aichi 4448585, Japan;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);
  • 原文格式 PDF
  • 正文语种 eng
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