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Growth mechanism of an icosahedral quasicrystal and solute partitioning in a Mg-rich Mg-Zn-Y alloy

机译:富镁Mg-Zn-Y合金中二十面体准晶体的生长机理及溶质分配

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摘要

The growth mechanism of an icosahedral quasicrystal and solute partitioning in a Mg-rich Mg-Zn-Y alloy were investigated. It is found that the preferred growth directions of the icosahedral quasicrystalline phase (Ⅰ-phase) are along 5-fold axes and the planes perpendicular to the 5-fold axes grow in a facet manner. Due to the local compositional change at the solid/ liquid interface, the planar growth is gradually replaced by cellular growth. During the nucleation of the primary Ⅰ-phase, on a microscale, the distribution of the Y element is changed and concentrated along 5-fold directions in the remaining liquid. If the cooling rate is relatively slow, there will be more Y element in the remaining liquid after the formation of the primary Ⅰ-phase. It causes that (Ⅰ-phase + α-Mg) eutectic structures form around the primary Ⅰ-phase. Almost all the Y element is exhausted after this stage. Especially, under a relatively slow cooling rate, the solute partitioning occurs during the growth process of the primary Ⅰ-phase, which leads to the microshrinkage cavity and crack defects at the edge of the primary Ⅰ-phase.
机译:研究了富镁Mg-Zn-Y合金中二十面体准晶体的生长机理和溶质分配。发现二十面体准晶相(Ⅰ相)的优选生长方向沿5倍轴,且垂直于5倍轴的平面成小平面生长。由于固/液界面处的局部组成变化,平面生长逐渐被细胞生长所取代。在一级Ⅰ相成核过程中,Y元素的分布发生了变化,并在剩余的液体中沿5倍方向集中。如果冷却速度相对较慢,则在形成初级Ⅰ相后,剩余液体中就会有更多的Y元素。导致在初级Ⅰ相周围形成(Ⅰ相+ α-Mg)共晶结构。在此阶段之后,几乎所有的Y元素都被耗尽。特别是在相对较慢的冷却速度下,溶质在第一相的生长过程中发生了分配,这导致了第一相边缘的微缩腔和裂纹缺陷。

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  • 来源
    《Journal of Materials Research》 |2014年第8期|942-949|共8页
  • 作者单位

    School of Materials Science and Engineering, University of Jinan, Jinan 250022, People's Republic of China;

    School of Materials Science and Engineering, University of Jinan, Jinan 250022, People's Republic of China;

    School of Materials Science and Engineering, University of Jinan, Jinan 250022, People's Republic of China;

    School of Materials Science and Engineering, University of Jinan, Jinan 250022, People's Republic of China;

    School of Materials Science and Engineering, University of Jinan, Jinan 250022, People's Republic of China;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);
  • 原文格式 PDF
  • 正文语种 eng
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