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Preparation of Cu-doped y-Fe_2O_3 nanowires with high coercivity by chemical vapor deposition

机译:化学气相沉积法制备高矫顽力的掺Cu y-Fe_2O_3纳米线

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摘要

Iron oxides, including maghemite (γ-Fe_2O_3) and magnetite (Fe_3O_4), have been widely applied in many fields. For technological advances in the future, further improvements of their ferromagnetic properties are desirable. The development of iron ferrites with a large coercive field (H_c) is one of issues of consequence. For ferrites, however, enlarging the H_c value is not easy because of their low magnetocrystalling anisotropy constant. Here we report single-crystalline Cu-doped γ-Fe_2O_3 nanowires in which the controlled diameter (70-100 nm) and the graded Cu dopant (7,10, and 15%) are directly obtained by a simple chemical vapor deposition technique. In particular, the coercive value (over 2 T) of 10% Cu-doped Y-Fe_2O_3 nanowires is much higher than that (<80 Oe) of undoped γ-Fe_2O_3 nanowires at room temperature. On the basis of the experimental magnetization data, the achievement of such a higher coercive field of Cu-doped γ-Fe_2O_3 (10%) nanowires is tentatively suggested.
机译:包括磁赤铁矿(γ-Fe_2O_3)和磁铁矿(Fe_3O_4)的氧化铁已广泛应用于许多领域。为了将来的技术进步,需要进一步改善其铁磁性能。具有大矫顽场(H_c)的铁氧体的发展是后果的问题之一。但是,对于铁氧体,由于其磁晶各向异性常数低,因此增大H_c值并不容易。在这里,我们报告单晶掺杂Cu的γ-Fe_2O_3纳米线,其中通过简单的化学气相沉积技术直接获得可控制的直径(70-100 nm)和渐变的Cu掺杂剂(7,10和15%)。特别地,在室温下,掺杂10%Cu的Y-Fe_2O_3纳米线的矫顽值(超过2 T)远高于未掺杂γ-Fe_2O_3纳米线的矫顽值(<80 Oe)。根据实验磁化数据,初步提出了实现这种较高的Cu掺杂γ-Fe_2O_3(10%)纳米线矫顽场的方法。

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  • 来源
    《Journal of Materials Research》 |2011年第13期|p.1634-1638|共5页
  • 作者单位

    Key Laboratory for Special Functional Materials of Ministry of Education, Henan University, Kaifeng 475004, People's Republic of China;

    Key Laboratory for Special Functional Materials of Ministry of Education, Henan University, Kaifeng 475004, People's Republic of China;

    Key Laboratory for Special Functional Materials of Ministry of Education, Henan University, Kaifeng 475004, People's Republic of China;

    Key Laboratory for Special Functional Materials of Ministry of Education, Henan University, Kaifeng 475004, People's Republic of China;

    Key Laboratory for Special Functional Materials of Ministry of Education, Henan University, Kaifeng 475004, People's Republic of China;

    Key Laboratory for Special Functional Materials of Ministry of Education, Henan University, Kaifeng 475004, People's Republic of China;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);
  • 原文格式 PDF
  • 正文语种 eng
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