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Diamond deposition on Ni/Ni-diamond coated stainless steel substrate

机译:镍/镍-金刚石涂层不锈钢基底上的金刚石沉积

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摘要

Electrodeposited Ni and Ni-diamond composite layers were used as diffusion barriers for Fe to facilitate the diamond growth on stainless steel substrates. Raman spectroscopy and scanning electron microscopy show the formation of good quality diamond crystallites by chemical vapor deposition. X-ray diffraction results indicate that the expansion of Ni unit cell has taken place due to the formation of the Ni-C solid solution. This observation is also well suppofted by x-ray photoelectron spectroscopy studies. The lattice constant of the expanded Ni unit cell matches closely with the diamond, and this may be helpful in explaining the epitaxial growth of diamond on single-crystal Ni observed by others.
机译:电沉积的Ni和Ni金刚石复合层用作Fe的扩散阻挡层,以促进金刚石在不锈钢基材上的生长。拉曼光谱和扫描电子显微镜显示通过化学气相沉积形成了高质量的金刚石微晶。 X射线衍射结果表明,由于Ni-C固溶体的形成,Ni晶胞已经发生膨胀。 X射线光电子能谱研究也很好地支持了这一观察结果。膨胀的Ni晶胞的晶格常数与金刚石紧密匹配,这可能有助于解释他人观察到的金刚石在单晶Ni上的外延生长。

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