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首页> 外文期刊>Journal of materials science >Effect of chromium ions on the structural, magnetic, and optical properties of manganese-zinc ferrite nanoparticles
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Effect of chromium ions on the structural, magnetic, and optical properties of manganese-zinc ferrite nanoparticles

机译:铬离子对铁氧体纳米粒子结构,磁性和光学性质的影响

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摘要

The present work describes the synthesis of Mn_(0.5)Zn_(0.5)Cr_xFe_(2-x)O_4 (x = 0.1, 0.2, 0.3) ferrite nanoparticles by solution combustion method and their detailed structural, electrical, magnetic, and optical characterizations. X-ray pattern represents the creation of a single spinel structure. In addition to this, the distribution of cations is also approximated from X-ray study which is then authenticated by the magnetization technique also. The crystalline size (23-21 nm) and lattice parameter (8.39-8.30 A) are found to shrink with the rise in chromium ions. A decrease in saturation magnetization (0.80-0.64 emu/g) and remanent magnetization (0.05-0.03 emu/g) is found with the rise in chromium ions, while the coercivity is found to increase (83-123 Oe) through the adding of chromium ions. FTIR predicted the two absorption bands (v_1 and v_2) near 600 and 400 cm~(-1). Dielectric constant and loss tangent were observed to decrease with an increase in frequency, whereas AC conductivity attains a nearly constant value at a lower frequency and observed to increase at higher frequencies with the addition of dopant.
机译:本作工作描述了通过溶液燃烧方法及其详细的结构,电,磁性和光学表征合成Mn_(0.5)Zn_(0.5)Zn_(0.5)CR_FE_(2-X)O_4(X = 0.1,0.2,0.3)的合成。 X射线图案代表了单尖晶石结构的创建。除此之外,阳离子的分布也从X射线研究近似,然后通过磁化技术进行认证。发现结晶尺寸(23-21nm)和晶格参数(8.39-8.30a)以铬离子的升高缩小。在铬离子的上升中发现饱和磁化强度(0.80-0.64 emu / g)和剩余磁化(0.05-0.03 emu / g)的降低,同时发现矫顽力增加(83-123 oe)通过加入增加铬离子。 FTIR预测了600和400cm〜(-1)附近的两个吸收带(V_1和V_2)。观察到频率恒定和损耗切线随着频率的增加而降低,而交流电导率以较低频率的较低频率达到几乎恒定的值,并且观察到以掺杂剂的增加以较高频率增加。

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  • 来源
    《Journal of materials science》 |2020年第19期|16959-16967|共9页
  • 作者单位

    Department of Physics Chandigarh University Gharuan Mohali Punjab India;

    King Abdullah Institute for Nanotechnology King Saud University P.O. Box 2455 Riyadh 11451 Saudi Arabia;

    Department of Physics College of Science King Saud University P.O. Box 2455 Riyadh 1 1451 Saudi Arabia;

    Department of Physics Chandigarh University Gharuan Mohali Punjab India;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);
  • 原文格式 PDF
  • 正文语种 eng
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