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Facile Synthesis of CuO Semiconductor Nanorods for Time Dependent Study of Dye Degradation and Bioremediation Applications

机译:用于染料降解和生物修复应用的时变研究的CuO半导体纳米棒的简便合成

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The manuscript reports facile one step synthesis of CuO semiconductor nanorods by solgel aaproach for photocatalytic and bioremediation applications. Spectroscopic characterization along with X-ray diffractometry and electron microscopy studies confirmed the formation of nanorods with 12 to 14 nm diameter and 50-100 nm length. As synthesized nanorods were subjected to photocatalytic degradation of dyes viz. Methylene Orange (MO), Methylene Blue (MB), Eriochrome Black T (ET) and Congo Red (CR) in a time bound study. Comparative analysis of the data depicted that time taken for degradation of equal amount of CR was more compared to the other three dyes owing to its high molecular weight and lower diffusion rate in aqueous medium. Subsequently, the antibacterial properties of the nanorods were investigated against the gram negative Escherichia coli and gram positive Bacillus bacteria. Zone of clearance was observed in disk diffusion assays, thereby confirming the antibacterial characteristics of the nanorods. These nanorods thus hold great promise as a simple, selective and a sensitive analytical platform for the effective bio-monitoring and photocatalyst for dye degradation.
机译:该手稿报告了通过Solgel制备方法可轻松一步合成CuO半导体纳米棒,用于光催化和生物修复应用。光谱表征以及X射线衍射和电子显微镜研究证实了直径12至14 nm,长度50-100 nm的纳米棒的形成。当合成的纳米棒经受染料的光催化降解时。一项限时研究中的亚甲基橙(MO),亚甲基蓝(MB),铬铁黑T(ET)和刚果红(CR)。数据的比较分析表明,等量的CR降解所需的时间比其他三种染料要多,这是因为其分子量高且在水性介质中的扩散速率较低。随后,研究了纳米棒对革兰氏阴性大肠杆菌和革兰氏阳性芽孢杆菌的抗菌性能。在圆盘扩散试验中观察到清除区,从而确认了纳米棒的抗菌特性。因此,这些纳米棒作为用于染料降解的有效生物监测和光催化剂的简单,选择性和灵敏的分析平台,具有广阔的前景。

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