Charge-Transfer Complexes Between Iodine and Substituted Thioureas: Determination of Thermodynamic and Spectroscopic Properties

Cornelia Fooken; Wolfram Baumann

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Charge-Transfer Complexes Between Iodine and Substituted Thioureas: Determination of Thermodynamic and Spectroscopic Properties

机译：碘和取代的硫脲之间的电荷转移络合物：热力学和光谱性质的确定

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摘要

15 iodine complexes with substituted thioureas were investigated in dichloromethane solution by UV-visible spectroscopy, and their equilibrium constants, reaction enthalpies and molar absorption coefficients were determined. The influence of the substituents on the properties of the charge-transfer complexes is examined. A critical discussion of previously published data is given, where comparable data are available.

机译：在二氯甲烷溶液中用紫外-可见光谱法研究了15种碘与取代的硫脲的络合物，并确定了它们的平衡常数，反应焓和摩尔吸收系数。研究了取代基对电荷转移配合物性能的影响。在可获得可比较数据的情况下，对以前发布的数据进行了严格的讨论。

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《Zeitschrift fur Naturforschung. A, A journal of physical sciences》 |1996年第2期|p.116-122|共7页
作者
Cornelia Fooken; Wolfram Baumann;
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Institut fuer Physikalische Chemie, Universitaet Mainz, D-55099 Mainz;

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正文语种 eng
中图分类物理学;
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Charge-Transfer Complexes Between Iodine and Substituted Thioureas: Determination of Thermodynamic and Spectroscopic Properties

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