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Red and blue emitting borate phosphor excited by near Ultraviolet Light

机译:近紫外光激发的红色和蓝色发射硼酸磷光体

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摘要

A highly intense reddish-orange and blue emitting borate phosphors YAl_3(BO_3)_4:Sm~(3+) and LaMgB_5_ O_(10):Ce~(3+) have been synthesized by a combustion synthesis method using urea as a fuel. Their luminescent properties have been studied over the 200-450 nm excitation range. The excitation and emission spectra of these phosphors were measured by a HITACHI F-7000 fluorescence spectrophotometer. The emission spectrum of Sm~(3+) in YAl_3(-BO_3)_4 phosphor monitored for 402 nm excitation composed of 564, 600, and 648 nm emission peaks, and the excitation spectra monitored at 600 nm emission shows peaks at 345, 362, 375,402, 421 and 445 nm. The emission spectrum of Ce~(3+) in LaMgB_5O_(10) phosphor exhibits a symmetrical band centered around 430 nm and excitation spectra monitored at 430 nm emission shows peaks at 272, 326 and 372 nm. The phosphors YAl_3(BO_3)_4:Sm~(3+) and LaMgB_5O_(10):Ce~(3+) can be a promising red and blue-emitting phosphor for UV LED applications.
机译:已经通过使用尿素作为燃料的燃烧合成方法合成了高强度的红橙色和蓝色发射的硼酸磷光体YAl_3(BO_3)_4:Sm〜(3+)和LaMgB_5_O_(10):Ce〜(3+)。已经在200-450 nm的激发范围内研究了它们的发光特性。这些荧光粉的激发和发射光谱通过HITACHI F-7000荧光分光光度计测量。 YAl_3(-BO_3)_4荧光粉中Sm〜(3+)的发射光谱由564、600和648 nm发射峰组成,监测402 nm激发,在600 nm发射下监测的激发谱显示在345、362处有峰,375,402、421和445 nm。 LaMgB_5O_(10)荧光粉中Ce〜(3+)的发射光谱显示出一个以430 nm为中心的对称谱带,在430 nm处监测到的激发光谱显示出在272、326和372 nm处的峰值。磷光体YAl_3(BO_3)_4:Sm〜(3+)和LaMgB_5O_(10):Ce〜(3+)可能是用于UV LED应用的有前途的红色和蓝色发射磷光体。

著录项

  • 来源
    《Journal of Optics》 |2017年第2期|91-94|共4页
  • 作者单位

    Toshniwal ACS College, Sengaon, Hingoli 431542, India;

    Department of Physics, Sant Gadge Baba Amravati University, Amravati 444602, India;

    Department of Physics, Shri Shivaji Science College, Amravati 444601, India;

    Department of Physics, Sant Gadge Baba Amravati University, Amravati 444602, India;

  • 收录信息 美国《工程索引》(EI);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    Borates; Photoluminescence; Combustion; Near UV LED;

    机译:硼酸盐;光致发光;燃烧;近紫外LED;

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