STRUCTURAL STUDIES OF PHOSPHORAMIDATES. CONFORMATIONAL PREFERENCES AND HYDROGEN BONDING

HUIJIE WAN; AGNES M. MODRO; TOM A. MODRO; SUSAN BOURNE; LUIGI R. NASSIMBENI

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STRUCTURAL STUDIES OF PHOSPHORAMIDATES. CONFORMATIONAL PREFERENCES AND HYDROGEN BONDING

机译：磷酸酰胺的结构研究。构型偏好和氢键

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The x-ray molecular structures of five chiral phosphoramidates derived from N-phosphorylated nitrogen mustard were determined and the molecular parameters are discussed. The value of the torsion angle of the O=P—N—H function which determines the packing of the molecules was found to determine also the ability of a substrate to form diastereomeric hydrogen-bonded complexes with optically active acids.

机译：确定了5种衍生自N-磷酸化氮芥的手性氨基磷酸酯的X射线分子结构，并讨论了分子参数。发现确定分子的堆积的O ＝ PNH函数的扭转角的值也确定了底物形成与旋光性酸的非对映异构氢键合的配合物的能力。

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来源
《Journal of Physical Organic Chemistry》 |1996年第11期|p.739-745|共7页
作者
HUIJIE WAN; AGNES M. MODRO; TOM A. MODRO; SUSAN BOURNE; LUIGI R. NASSIMBENI;
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Centre for Heteroatom Chemistry, Department of Chemistry, University of Pretoria, Pretoria 0002, South Africa;

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正文语种 eng
中图分类有机化学一般性问题;
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STRUCTURAL STUDIES OF PHOSPHORAMIDATES. CONFORMATIONAL PREFERENCES AND HYDROGEN BONDING

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