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Rapid charge and discharge property of high capacity lithium ion battery applying three-dimensionally patterned electrode

机译:具有三维图案化电极的高容量锂离子电池的快速充放电性能

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摘要

The cells applied with a three-dimensionally (3D) patterned Li_4Ti_5O_(12) (LTO) electrode showed good performance as a rechargeable lithium-ion battery. The 3D-pattemed electrode was fabricated with a printing apparatus and has many lined patterns with a high aspect ratio standing in line on a current collector. The cell using 3D-patterned electrode showed much better rate capability than that using a conventional flat electrode. In this research, cyclic voltammetry was carried out to investigate the mechanism realizing the high rates of charging and discharging in 3D-patterned electrode. Various types of line patterns were fabricated for 3D electrode by using LTO electrode slurry, and the influences of basic specifications of electrode structure (the space between two neighboring electrode lines, the height and width of electrode) on the charge and discharge characteristics were evaluated to optimize the electrode pattern. In addition, the electrode performance was discussed from the viewpoints of ohmic resistance and charge-transfer resistance of the cells with 3D-patterned and conventional flat electrodes.
机译:施加了三维(3D)图案化Li_4Ti_5O_(12)(LTO)电极的电池显示出可充电锂离子电池良好的性能。用印刷设备制造3D图案化的电极,并且该电极具有许多排列的图案,这些图案具有高纵横比并排排列在集电器上。使用3D图案电极的电池比使用常规平面电极的电池具有更高的倍率能力。在这项研究中,进行了循环伏安法以研究在3D图案电极中实现高速率充放电的机理。使用LTO电极浆料制造3D电极的各种线型,并评估电极结构的基本规格(两条相邻电极线之间的间距,电极的高度和宽度)对充电和放电特性的影响,优化电极图案。另外,从具有3D图案的和常规的平面电极的电池的欧姆电阻和电荷转移电阻的角度讨论了电极性能。

著录项

  • 来源
    《Journal of power sources》 |2014年第15期|244-249|共6页
  • 作者单位

    Dainippon SCREEN Mfg. Co., Ltd, 322 Furukawa-cho, Hazukashi, Fushimi-ku, Kyoto 612-8486, Japan;

    Dainippon SCREEN Mfg. Co., Ltd, 322 Furukawa-cho, Hazukashi, Fushimi-ku, Kyoto 612-8486, Japan;

    Dainippon SCREEN Mfg. Co., Ltd, 322 Furukawa-cho, Hazukashi, Fushimi-ku, Kyoto 612-8486, Japan;

    Dainippon SCREEN Mfg. Co., Ltd, 322 Furukawa-cho, Hazukashi, Fushimi-ku, Kyoto 612-8486, Japan;

    Dainippon SCREEN Mfg. Co., Ltd, 322 Furukawa-cho, Hazukashi, Fushimi-ku, Kyoto 612-8486, Japan;

    Dainippon SCREEN Mfg. Co., Ltd, 322 Furukawa-cho, Hazukashi, Fushimi-ku, Kyoto 612-8486, Japan;

    Graduate School of Urban Environmental Sciences, Tokyo Metropolitan University, 1-1 Minami-Osawa, Hachioji, Tokyo 192-0397, Japan;

    Graduate School of Urban Environmental Sciences, Tokyo Metropolitan University, 1-1 Minami-Osawa, Hachioji, Tokyo 192-0397, Japan;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    Lithium-ion battery; Lithium titanium oxide; Three-dimensionally patterned electrode; Rate capability;

    机译:锂离子电池;锂钛氧化物;三维图案化电极;评分能力;

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