Thermal decomposition kinetics of tetraalkylammonium and dimethylpyridinium salts of the complex anion bis(1,3-dithiole-2-thione-4,5-dithiolate) bismuthate (−1)

Ana Maria Rocco; James L. Wardell; Robson Pacheco Pereira

首页> 外文期刊>Journal of Thermal Analysis and Calorimetry >Thermal decomposition kinetics of tetraalkylammonium and dimethylpyridinium salts of the complex anion bis(1,3-dithiole-2-thione-4,5-dithiolate) bismuthate (−1)

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Thermal decomposition kinetics of tetraalkylammonium and dimethylpyridinium salts of the complex anion bis(1,3-dithiole-2-thione-4,5-dithiolate) bismuthate (−1)

机译：络合双（1,3-二硫代-2-硫酮-4,5-二硫代）（-1）阴离子的四烷基铵盐和二甲基吡啶盐的热分解动力学

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In the present work, thermal decomposition kinetics of tetraalkylammonium and 1,4-dimethylpyridinium salts of the complex anion bis(1,3-dithiole-2-thione-4,5-dithiolate) bismuthate ([Bi(dmit)₂]−) are addressed. Kinetic parameters for the decomposition reactions were obtained utilizing the Ozawa and Coats–Redfern (CR) models. Entropy, enthalpy, and free energy of decomposition processes were calculated from the CR results, providing information on the thermodynamic characteristics of the processes. The most probable mechanisms of thermal decomposition were indicated for the studied systems, along with their kinetic and thermodynamic parameters.

机译：在本工作中，配合物双（1,3-二硫代-2--2-硫酮-4,5-二硫代）铋酸铋（[Bi（dmit）2）的四烷基铵盐和1,4-二甲基吡啶盐的热分解动力学] -）。使用Ozawa和Coats-Redfern（CR）模型获得了分解反应的动力学参数。根据CR结果计算了分解过程的熵，焓和自由能，从而提供了有关该过程的热力学特性的信息。对于所研究的系统，指出了最可能的热分解机理，以及它们的动力学和热力学参数。

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《Journal of Thermal Analysis and Calorimetry》 |2012年第1期|p.345-354|共10页
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Ana Maria Rocco; James L. Wardell; Robson Pacheco Pereira;
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1. Thermal decomposition kinetics of tetraalkylammonium and dimethylpyridinium salts of the complex anion bis(1,3-dithiole-2-thione-4,5-dithiolate) bismuthate (-1) (Conference Paper) [J] . Rocco A.M., Wardell J.L., Pereira R.P. Journal of thermal analysis and calorimetry . 2012,第1期

机译：络合双（1,3-二硫代-2-硫酮-4,5-二硫代）（-1）阴离子的四烷基铵盐和二甲基吡啶盐的热分解动力学（会议论文）
2. Synthesis and properties of bis(1,3-dithiole-2-thione-4,5-dithiolato)bismuthate(1-) salts,[Q][Bi(dmit)_2]. Crystal structure of [AsPh_4][Bi(dmit)_2].1/2DMSO: comparison of the solid state strcutures of [Q][Bi(dmit)_2] and [Q][Sb(dmit)_2] [J] . Nadia Maria Comerlato, Luiz Antonio Sodre Costa, R.Alan Howie, Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2001,第5期

机译：双（1,3-二硫代-2-硫酮-4,5-二硫代Lato）铋（1-）盐[Q] [Bi（dmit）_2]的合成与性能。 [AsPh_4] [Bi（dmit）_2] .1 / 2DMSO的晶体结构：[Q] [Bi（dmit）_2]和[Q] [Sb（dmit）_2]固态结构的比较
3. Bilayer mott system based on Ni(dmit) _2 (dmit = 1,3-dithiole-2-thione-4,5-dithiolate) anion radicals: Two isostructural salts exhibit contrasting magnetic behavior [J] . Kusamoto T., Yamamoto H.M., Tajima N., Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2012,第21期

机译：基于Ni（dmit）_2（dmit = 1,3-二硫代-2-硫酮-4,5-二硫代）阴离子基团的双层莫特系统：两种同构盐表现出相反的磁性
4. A Novel Dimeric Unsymmetrical Dithiolene Zinc (Ⅱ) Complex of 1,3-Dithiole-2-thione-4,5-dithiolate with Third-Order Nonlinear Optical Property [C] . Cai-MingLiu China-Japan joint symposium on conduction and photoconduction in organic solids and related phenomena;CJOSS-7 . 2001

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5. DIALKYL BIS(AMIDE) COMPLEXES OF TITANIUM, ZIRCONIUM, AND HAFNIUM: THERMAL DECOMPOSITION AND INSERTION REACTIONS (BISAMIDE) [D] . PLANALP, ROY PAUL 1983

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6. The thermal stability of oligonucleotide duplexes is sequence independent in tetraalkylammonium salt solutions: application to identifying recombinant DNA clones. [O] . K A Jacobs, R Rudersdorf, S D Neill, 1988

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7. Development of π-Electron Systems Based on M(dmit)2 (M = Ni and Pd; dmit: 1,3-dithiole-2-thione-4,5-dithiolate) Anion Radicals [O] . Reizo Kato 2014

机译：基于M（DMIT）2（M = Ni和Pd; DMIT：1,3-二孔-2-尖峰-4,5-二硫酸盐）阴离子自由基的π电子系统的研制

Thermal decomposition kinetics of tetraalkylammonium and dimethylpyridinium salts of the complex anion bis(1,3-dithiole-2-thione-4,5-dithiolate) bismuthate (−1)

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