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Electronic defect states at annealed metal/4H-SIC interfaces

机译:退火金属/ 4H-SIC界面处的电子缺陷状态

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We have used low energy electron-excited nanoscale luminescence spectroscopy (LEEN) to study the formation of electronic surface states at metal/4H-SiC contacts. These junctions were formed using both low and high reactivity metals to study how the nature of interface chemical bonding affects the interface state formation. We observe evidence for the formation and removal of localized states at energies that have been associated with morphological SiC defects. Metals such as Au and Ag with no strong chemical reactivity exhibited the most pronounced changes. Conversely, chemically-reactive metals such as Ti and Ni exhibited only minor changes and only with high temperature annealing. These observations suggest that native defects rather then metal-specific chemical bonding dominate the interface electronic features.
机译:我们已经使用低能电子激发的纳米级发光光谱(LEEN)来研究金属/ 4H-SiC接触处电子表面态的形成。这些连接是使用低反应性金属和高反应性金属形成的,以研究界面化学键的性质如何影响界面态的形成。我们观察到了与形态学SiC缺陷相关的能量中局部状态的形成和去除的证据。没有强化学反应性的金属,如金和银,表现出最明显的变化。相反,化学反应性金属(例如Ti和Ni)仅表现出很小的变化,并且仅在高温退火的情况下表现出。这些观察结果表明,天然缺陷而不是金属特异性化学键主导了界面电子特征。

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