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Improvement of Furfural Production from Concentrated PreHydrolysis Liquor (PHL) of a Kraft-Based Hardwood Dissolving Pulp Production Process

机译:牛皮纸硬木浆粕生产工艺的浓缩预水解液(PHL)改善糠醛生产

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摘要

Hemicelluloses present in the prehydrolysis liquor (PHL) of the hardwood kraft-based dissolving pulp production process can be utilized in the production of furfural, which is an important renewable, non-petroleum-based platform chemical. A lower furfural yield was observed from the concentrated sugars in PHL in acetic-acid-catalyzed systems. The reaction rate of sugar consumption and furfural destruction in PHL was higher than those of model xylan and xylose systems, which may be due to the side-reactions of lignin with sugars and carbonization of oligomeric sugars. In order to minimize these side-reactions, a steam-stripping method of generated furfural was adopted. The results showed that the method was effective in increasing the furfural yield (41.5%) from the concentrated PHL.
机译:存在于硬木硫酸盐基溶解纸浆生产工艺的预水解液(PHL)中的半纤维素可用于糠醛的生产,糠醛是一种重要的可再生的,非石油基的平台化学品。在乙酸催化体系中,从PHL中的浓缩糖中观察到较低的糠醛收率。 PHL中糖消耗和糠醛破坏的反应速率高于模型木聚糖和木糖系统,这可能是由于木质素与糖的副反应和低聚糖的碳化所致。为了使这些副反应最小化,采用了汽提法产生糠醛。结果表明,该方法可有效提高浓缩PHL的糠醛收率(41.5%)。

著录项

  • 来源
    《Journal of Wood Chemistry and Technology》 |2015年第6期|260-269|共10页
  • 作者单位

    Tianjin Univ Sci & Technol, Tianjin Key Lab Pulp & Paper, Tianjin, Peoples R China|Univ New Brunswick, Dept Chem Engn, Limerick Pulp & Paper Ctr, Fredericton, NB E3B 5A3, Canada;

    Tianjin Univ Sci & Technol, Tianjin Key Lab Pulp & Paper, Tianjin, Peoples R China;

    Univ New Brunswick, Dept Chem Engn, Limerick Pulp & Paper Ctr, Fredericton, NB E3B 5A3, Canada|BCSIR Labs, Pulp & Paper Res Div, Dhaka, Bangladesh;

    Tianjin Univ Sci & Technol, Tianjin Key Lab Pulp & Paper, Tianjin, Peoples R China|Univ New Brunswick, Dept Chem Engn, Limerick Pulp & Paper Ctr, Fredericton, NB E3B 5A3, Canada;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    Biorefinery; prehydrolysis liquor; sugars conversion; acetic acid; furfural yield;

    机译:生物炼制;预水解液;糖转化;乙酸;糠醛收率;

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