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Pyrolysis Products of Lignin in Open and Sealed Vessels Studied by Py-GC-MS

机译:用Py-GC-MS研究木质素在开放式和密封容器中的热解产物

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摘要

The pyrolysis products of lignin in open and sealed vessels were studied by pyrolysis-gas chromatography-mass spectrometry (Py-GC-MS). Several kinds of phenolic derivatives were observed in the pyrolysates in both treatments, while phenolic compounds with alkenyl or acetyl groups had higher relative contents in the open vessel than those in the sealed vessel. Phenol and its alkyl or mono-methoxy substituted derivatives become the main pyrolysis products in the sealed vessel. Most of the lignin pyrolysis products in the open vessel could be detected by Py-GC-MS, but some active products would go through further reaction in the sealed vessel.
机译:通过热解-气相色谱-质谱法(Py-GC-MS)研究木质素在敞口和密封容器中的热解产物。在两种处理中,在热解物中均观察到几种酚类衍生物,而带有烯基或乙酰基的酚类化合物在敞口容器中的相对含量高于密封容器中的相对含量。苯酚及其烷基或单甲氧基取代的衍生物成为密封容器中的主要热解产物。敞口容器中的大多数木质素热解产物可通过Py-GC-MS检测,但一些活性产物会在密闭容器中进一步反应。

著录项

  • 来源
  • 作者

    Y. FU; K. KATO; H. OHTANI; Y. CHEN;

  • 作者单位

    School of Science, Beijing University of Chemical Technology, Beijing, China;

    Department of Material Science and Engineering, Graduate School of Engineering, Nagoya Institute of Technology, Nagoya, Japan;

    Department of Material Science and Engineering, Graduate School of Engineering, Nagoya Institute of Technology, Nagoya, Japan;

    School of Science, Beijing University of Chemical Technology, Beijing 100029, China;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    Lignin; pyrolysis products; Py-GC-MS; open vessel; sealed vessel;

    机译:木质素热解产物;py-GC-MS;开敞式船;密封容器;

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