Polymerization Reactor Modeling in Industry

Philipp A. Mueller; John R. Richards; John P. Congalidis

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Polymerization Reactor Modeling in Industry

机译：工业中的聚合反应器建模

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摘要

This paper provides an industrial perspective for the development of polymer reaction engineering models and their application to create new materials, products, and improved or novel processes. The challenges specific to polymer reactor modeling are discussed in the context of articles and books that the authors have found useful. Four components of a polymer reactor model (kinetics, thermodynamics, transport effects, and particle dynamics) are discussed with illustrative examples. Finally typical outputs of polymer reactor models are shown to demonstrate that a first principles model supported and validated by experiments can be a very powerful tool for fundamental understanding of polymer reactors and is a recommended alternative to empirical methods and experimentation alone.

机译：本文为聚合物反应工程模型的开发及其在创建新材料，新产品以及改进或新颖工艺中的应用提供了工业前景。作者发现有用的文章和书籍中讨论了聚合物反应器建模所特有的挑战。通过举例说明了聚合物反应器模型的四个组成部分（动力学，热力学，传输效应和颗粒动力学）。最后显示了聚合物反应器模型的典型输出，以证明通过实验支持和验证的第一个原理模型可以成为非常了解聚合物反应器的有力工具，并且是经验方法和实验的推荐替代方法。

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来源
《Macromolecular reaction engineering》 |2011年第8期|p.261-277|共17页
作者
Philipp A. Mueller; John R. Richards; John P. Congalidis;
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作者单位

E. I. du Pont de Nemours and Company, Experimental Station,Wilmington, Delaware 19880, USA;

E. I. du Pont de Nemours and Company, Experimental Station,Wilmington, Delaware 19880, USA;

E. I. du Pont de Nemours and Company, Experimental Station,Wilmington, Delaware 19880, USA;

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原文格式 PDF
正文语种 eng
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关键词
kinetics; mathematical modeling; polymer; polymerization; reactor; structure-property relations; thermodynamics;

机译：动力学;数学建模;聚合物;聚合;反应堆;结构-财产关系;热力学;

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专利

1. Polymerization Reactor Modeling in Industry – An Overview of Concepts and Tools [J] . Philipp A. Mueller, John R. Richards, Paul E. M. Wijnands Macromolecular Symposia . 2010,第1期

机译：工业中的聚合反应器建模–概念和工具概述
2. Polymerization reactor modeling in industry - An overview of concepts and tools [J] . Mueller P.A., Richards J.R., Wijnands P.E.M. Macromolecular symposia . 2010,第Null期

机译：工业中的聚合反应器建模-概念和工具概述
3. Prediction interval-based modelling of polymerization reactor:A new modelling strategy for chemical reactors [J] . Mohammad Anwar Hosen, Abbas Khosravi, Douglas Creighton, Journal of the Taiwan Institute of Chemical Engineers . 2014,第5期

机译：基于预测区间的聚合反应器建模：化学反应器的新建模策略
4. MODELING AND SIMULATION OF POLYMERIZATION OF LACTIDE TO POLYLACTIC ACID AND CO-POLYMERS OF POLYLACTIC ACID USING HIGH VISCOSITY KNEADER REACTORS [C] . Boyd T. Safril, George E. Schlager, Ziang Li Technical Conference of the Society of Plastics . 2014

机译：使用高粘度捏合器反应器的聚乳酸聚合对聚乳酸和共聚物的建模与模拟
5. Some challenges in ethylene polymerization: Particle overheating in gas phase reactors, and modeling ethylene polymerization over nickel-diimine catalysts. [D] . Lo, Dennis Pao-Chang. 2003

机译：乙烯聚合中的一些挑战：气相反应器中的颗粒过热，以及在镍二亚胺催化剂上模拟乙烯聚合。
6. Multienzyme Immobilized Polymeric Membrane Reactor for the Transformation of a Lignin Model Compound [O] . Rupam Sarma, Md. Saiful Islam, Mark P. Running, 2018

机译：固定化多酶聚合物膜反应器转化木质素模型化合物
7. Dynamic Modelling and Optimization of Polymerization Processes in Batch and Semi-batch Reactors. Dynamic Modelling and Optimization of Bulk Polymerization of Styrene, Solution Polymerization of MMA and Emulsion Copolymerization of Styrene and MMA in Batch and Semi-batch Reactors using Control Vector Parameterization Techniques. [O] . Ibrahim W. H. B. W. 2011

机译：分批和半分批反应器中聚合过程的动态建模和优化。动态和建模的苯乙烯本体聚合，MMA的溶液聚合和苯乙烯和MMA的乳液聚合在间歇和半间歇反应器中使用控制矢量参数化技术。

Polymerization Reactor Modeling in Industry

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