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首页> 外文期刊>Materials Chemistry and Physics. >Luminescence and vibrational characteristics of the submicro crystals of lanthanum orthophosphates and metaphosphates codoped with Er~(3+) and Yb~(3+) ions
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Luminescence and vibrational characteristics of the submicro crystals of lanthanum orthophosphates and metaphosphates codoped with Er~(3+) and Yb~(3+) ions

机译:掺有Er〜(3+)和Yb〜(3+)离子的正磷酸盐镧和偏磷酸盐镧的微晶体的发光和振动特性

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摘要

Er~(3+) and Yb~(3+) doped K_3La(PO_4)_2 ortho- and KLa(PO_3)_4 metaphosphates were synthesised by the solid state reaction method. The obtained powders were characterised by XRD method, IR and Raman spectroscopy as well as optical absorption spectroscopy. The emission spectra were measured and fluorescence decay studies were carried out at room temperature. The energy transfer from Yb~(3+) to Er~(3+) and two-photon up-conversion processes were observed and discussed. The influence of the ortho- and metaphosphate host on efficiency of the luminescence was discussed.
机译:通过固相反应法合成了Er〜(3+)和Yb〜(3+)掺杂的K_3La(PO_4)_2正磷酸盐和KLa(PO_3)_4偏磷酸盐。所得粉末通过XRD法,IR和拉曼光谱以及光吸收光谱进行表征。测量发射光谱,并在室温下进行荧光衰减研究。观察并讨论了从Yb〜(3+)到Er〜(3+)的能量转移以及双光子上转换过程。讨论了正磷酸盐和偏磷酸盐基质对发光效率的影响。

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  • 来源
    《Materials Chemistry and Physics.》 |2009年第1期|262-267|共6页
  • 作者单位

    Department of Inorganic Chemistry, Faculty of Engineering and Economics, Wroclaw University of Economics, 118/120 Komandorska str., 53-345 Wroclaw, Poland;

    Institute of Low Temperature and Structure Research, Polish Academy of Sciences, P.O. Box 1410, 50-950 Wroclaw, Poland;

    Institute of Low Temperature and Structure Research, Polish Academy of Sciences, P.O. Box 1410, 50-950 Wroclaw, Poland;

    Department of Bioorganic Chemistry, Faculty of Engineering and Economics, Wroclaw, University of Economics, 118/120 Komandorska str.,53-345 Wroclaw. Poland;

    Department of Inorganic Chemistry, Faculty of Engineering and Economics, Wroclaw University of Economics, 118/120 Komandorska str., 53-345 Wroclaw, Poland;

    Department of Inorganic Chemistry, Faculty of Engineering and Economics, Wroclaw University of Economics, 118/120 Komandorska str., 53-345 Wroclaw, Poland;

    Institute of Low Temperature and Structure Research, Polish Academy of Sciences, P.O. Box 1410, 50-950 Wroclaw, Poland Department of Bioorganic Chemistry, Faculty of Engineering and Economics, Wroclaw, University of Economics, 118/120 Komandorska str.,53-345 Wroclaw. Poland;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    inorganic compounds; infrared spectroscopy; luminescence; optical properties;

    机译:无机化合物红外光谱发光光学性质;

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