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Interaction between Fe_(66)Cr_(10)Nb_5B_(19) metallic glass and aluminum during spark plasma sintering

机译:FE_(66)CR_(10)NB_5B_(19)金属玻璃和铝之间的相互作用在火花等离子体烧结期间

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摘要

In the area of metal matrix composites, novel reinforcing options are currently being evaluated. Particles of amorphous alloys present an interesting possibility to reinforce soft metals. In the present work, the interaction between Fe_(66)Cr_(10)Nb_5B_(19) metallic glass and aluminum during spark plasma sintering (SPS) was studied for the first time. In order to trace the phase and microstructural changes upon sintering, mixtures containing 20 vol% and 50 vol% of metallic glass were subjected to SPS at 500-570°C. After SPS at 500°C,no reaction layer between the metallic glass particles and aluminum was observed. After SPS at 570°C,a reaction layer containing Fe_2Al_5 and FeAl_3 formed around the Fe-based cores. The Vickers hardness of composites obtained from mixtures containing 20 vol% Fe_(66)Cr_(10)Nb_5B_(19) at 540°C was 75 HV and increased to 280 HV after sintering at 570°Cdue to the formation of thicker reaction layers at the interface. The hardness of the composite sintered from the mixture containing 20 vol% Fe_(66)Cr_(10)Nb_5B_(19) at 570 °C was between the values predicted by Reuss and Voigt models. Comparison of results of SPS of the powder mixtures with those of SPS of a pre-compacted pellet and electric current-free annealing suggests that local heating at the interface caused by interfacial resistance may be an important factor influencing the reaction advancement at the interface and the formation of Al-containing intermetallics.
机译:在金属基质复合材料的区域中,目前正在评估新的增强选项。非晶合金颗粒具有增强软金属的有趣可能性。在本作工作中,第一次研究了Fe_(66)Cr_(10)Nb_5b_(19)金属玻璃和铝之间的相互作用在火花等离子体烧结期间(SPS)。为了追踪烧结时的相和微观结构变化,含有20体积%和50Vol%金属玻璃的混合物在500-570℃下进行SP。在500℃下SPS后,观察到金属玻璃颗粒和铝之间的反应层。在570℃下SPS之后,含有Fe_2Al_5和FEAL_3的反应层围绕Fe基芯形成。从540℃的含有20VOR%Fe_(66)Cr_(10)Nb_5b_(19)的混合物中获得的复合材料的硬度为75HV并在烧结以570°Clde的烧结后增加至280hv,以形成较厚的反应层界面。在570℃下,从含有20Vol%Fe_(66)Cr_(10)Nb_5b_(19)的混合物中的复合物的硬度在Reuss和Voigt模型预测的值之间。粉末混合物SPS的结果比较与预压制的颗粒和电流无电流退火的SPS的结果表明,由界面抗性引起的界面处的局部加热可能是影响界面处的反应进步的重要因素。形成含Al的金属间金属间金属间化合物。

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  • 来源
    《Materials Science and Engineering》 |2021年第2期|140165.1-140165.13|共13页
  • 作者单位

    Lavrentyev Institute of Hydrodynamics SB RAS Lavrentyev Ave. 15 Novosibirsk 630090 Russia Novosibirsk State Technical University K. Marx Ave. 20 Novosibirsk 630073 Russia Institute of Solid State Chemistry and Mechanochemistry SB RAS Kutateladze Str. 18 Novosibirsk 630128 Russia;

    Institute of Solid State Chemistry and Mechanochemistry SB RAS Kutateladze Str. 18 Novosibirsk 630128 Russia;

    Lavrentyev Institute of Hydrodynamics SB RAS Lavrentyev Ave. 15 Novosibirsk 630090 Russia;

    Novosibirsk State Technical University K. Marx Ave. 20 Novosibirsk 630073 Russia;

    Institute of Solid State Chemistry and Mechanochemistry SB RAS Kutateladze Str. 18 Novosibirsk 630128 Russia;

    Lavrentyev Institute of Hydrodynamics SB RAS Lavrentyev Ave. 15 Novosibirsk 630090 Russia Novosibirsk State Technical University K. Marx Ave. 20 Novosibirsk 630073 Russia;

    Lavrentyev Institute of Hydrodynamics SB RAS Lavrentyev Ave. 15 Novosibirsk 630090 Russia Novosibirsk State Technical University K. Marx Ave. 20 Novosibirsk 630073 Russia;

    Lavrentyev Institute of Hydrodynamics SB RAS Lavrentyev Ave. 15 Novosibirsk 630090 Russia;

    Institute of Solid State Chemistry and Mechanochemistry SB RAS Kutateladze Str. 18 Novosibirsk 630128 Russia;

    Novosibirsk State Technical University K. Marx Ave. 20 Novosibirsk 630073 Russia;

    School of Aerospace Transport and Manufacturing Cranfield University Cranfield MK43 0AL UK;

    Department of Materials Science and Engineering Federal University of Sao Carlos Via Washington Luiz Km 235 Sao Carlos SP 13565-905 Brazil;

    Department of Materials Science and Engineering Federal University of Sao Carlos Via Washington Luiz Km 235 Sao Carlos SP 13565-905 Brazil;

    Department of Materials Science and Engineering Federal University of Sao Carlos Via Washington Luiz Km 235 Sao Carlos SP 13565-905 Brazil;

    Department of Materials Science and Engineering Federal University of Sao Carlos Via Washington Luiz Km 235 Sao Carlos SP 13565-905 Brazil Grenoble Alpes University CNRS LEPMI and SIMAP F-38000 Grenoble France;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    Metal matrix composites; Sintering; Microstructure; Scanning electron microscopy; Hardness;

    机译:金属基复合材料;烧结;微观结构;扫描电子显微镜;硬度;

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