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首页> 外文期刊>Materials Science and Engineering >Flexible lignin-derived carbon nanofiber substrates functionalized with iron (Ⅲ) oxide nanoparticles as lithium-ion battery anodes
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Flexible lignin-derived carbon nanofiber substrates functionalized with iron (Ⅲ) oxide nanoparticles as lithium-ion battery anodes

机译:柔性木质素衍生的碳纳米纤维基底,经氧化铁(Ⅲ)纳米粒子功能化,可作为锂离子电池阳极

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摘要

To develop high-performance flexible anodes has become an emerging technological demand for the next generation of lithium-ion batteries (LIBs). In this study, flexible substrates consisting of randomly overlaid electrospun carbon nanofibers (ECNFs) with fiber diameters of similar to 200 nm and BET specific surface area of similar to 583m(2).g(-1) were made from lignin and polyvinyl alcohol by electrospinning followed by stabilization in air and carbonization in argon. After surface-functionalization with Fe2O3 nanoparticles, the resulting flexible ECNF/Fe2O3 nanostructures/electrodes exhibited enhanced lithiation/delithiation performance. Specifically, in lithium-ion half-cells with similar to 35 wt% Fe2O3 nanoparticles deposited on ECNF surfaces, the discharge capacities of similar to 951 mA.h.g(-1) in the first cycle and similar to 715 mA.h.g(-1) after 80 cycles were observed. This study presents a new approach for the fabrication of flexible LIB anodes by eliminating commonly used organic binders, metal substrates, and electrode slurries; furthermore, lignin that is a waste byproduct of cellulose industry has been successfully utilized in this approach.
机译:开发高性能的柔性阳极已成为下一代锂离子电池(LIB)的新兴技术需求。在这项研究中,由木质素和聚乙烯醇通过由木质素和聚乙烯醇制成的柔性基材,由随机覆盖的电纺碳纳米纤维(ECNF)制成,其纤维直径近似于200 nm,BET比表面积近似于583m(2).g(-1)。电纺丝,然后在空气中稳定并在氩气中碳化。在用Fe 2 O 3纳米颗粒进行表面官能化之后,所得的柔性ECNF / Fe 2 O 3纳米结构/电极表现出增强的锂化/脱锂性能。具体而言,在锂离子半电池中,其ECNF表面沉积了约35 wt%的Fe2O3纳米颗粒,其放电容量在第一个循环中类似于951 mA.hg(-1),而类似于715 mA.hg(-1) )观察80个循环后。这项研究提出了一种通过消除常用的有机粘合剂,金属基底和电极浆料来制造柔性LIB阳极的新方法。此外,作为纤维素工业的废副产物的木质素已经成功地用于该方法中。

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  • 来源
    《Materials Science and Engineering》 |2019年第2期|100-104|共5页
  • 作者单位

    South Dakota Sch Mines & Technol, Program Nanosci & Nanoengn, Rapid City, SD 57701 USA;

    South Dakota Sch Mines & Technol, Dept Chem & Appl Biol Sci, Rapid City, SD 57701 USA|South Dakota Sch Mines & Technol, Program Mat Engn & Sci, Rapid City, SD 57701 USA;

    South Dakota Sch Mines & Technol, Program Nanosci & Nanoengn, Rapid City, SD 57701 USA|South Dakota Sch Mines & Technol, Dept Chem & Appl Biol Sci, Rapid City, SD 57701 USA|South Dakota Sch Mines & Technol, Program Mat Engn & Sci, Rapid City, SD 57701 USA;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    Electrospinning; Flexible carbon nanofiber substrate; Lignin; Iron (III) oxide; Lithium-ion battery anode;

    机译:电纺丝;柔性碳纳米纤维基底;木质素;三氧化二铁;锂离子电池负极;

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