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Ce(Ⅲ) corrosion inhibitor release from silica and boehmite nanocontainers

机译:Ce(Ⅲ)缓蚀剂从二氧化硅和勃姆石纳米容器中释放

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Electrochemical impedance spectroscopy clearly appeared as a suitable technique to investigate the releasing properties of cerium (III) loaded on silica and boehmite nanocontainers. In this way the electrochemical behavior of the AA2024-T3 was evaluated by electrochemical impedance spectroscopy in a 0.045 mol L−1NaCl solution with nanocontainers containing the inhibitor. Results show that the inhibitor release is influenced by both the chemical nature and the morphology of the nanocontainers. The lower loading and release phenomena were observed for the mesoporous silica nanocontainers, whereas the inhibitor is liberated until 168 h from dense silica nanocontainers. Boehmite nanocontainers combine a good loading ratio with a longer release until the second week of immersion.
机译:电化学阻抗谱显然是研究负载在二氧化硅和勃姆石纳米容器上的铈(III)释放特性的合适技术。这样,通过电化学阻抗谱在带有含抑制剂的纳米容器的0.045 mol L-1NaCl溶液中的电化学阻抗谱来评估AA2024-T3的电化学行为。结果表明,抑制剂的释放受纳米容器的化学性质和形态的影响。对于中孔二氧化硅纳米容器,观察到较低的负载和释放现象,而抑制剂从致密二氧化硅纳米容器中释放直至168 h。勃姆石纳米容器具有良好的负载率和更长的释放时间,直至浸泡第二周。

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