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首页> 外文期刊>Materials Science and Engineering. B, Solid-State Materials for Advanced Technology >Synthesis, characterization and electrical properties of poly(o-toluidine)/multi-walled carbon nanotube composites
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Synthesis, characterization and electrical properties of poly(o-toluidine)/multi-walled carbon nanotube composites

机译:聚(邻甲苯胺)/多壁碳纳米管复合材料的合成,表征和电性能

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摘要

We described the synthesis of hydrochloric acid (HCl) doped poly(o-toluidine) (POT) with carboxylic groups containing multi-walled carbon nanotubes (c-MWNTs) via in situ polymerization. o-Toluidine monomers were adsorbed on the surface of MWNTs and polymerized to form POT/c-MWNT composites. Scanning electron microscopy (SEM) and transmission electron microscopy (TEM) images showed that both the thinner fibrous phase and the larger block phase could be observed. The individual fibrous phases had diameters about 100 nm, and therefore must be the carbon nanotubes (diameter 20-30 nm) coated by a POT layer. The structure of POT/c-MWNT composites was characterized by FT-IR, UV-vis spectra and X-ray diffraction patterns. The electrical conductivities of POT/c-MWNT composites were improved relative to those of POT without c-MWNTs.
机译:我们描述了通过原位聚合合成具有羧基的盐酸(HCl)掺杂的聚(邻甲苯胺)(POT),该多壁碳纳米管(c-MWNTs)。邻甲苯胺单体被吸附在MWNT的表面并聚合形成POT / c-MWNT复合材料。扫描电子显微镜(SEM)和透射电子显微镜(TEM)图像显示,可以观察到较细的纤维相和较大的嵌段相。各个纤维相的直径约为100 nm,因此必须是被POT层覆盖的碳纳米管(直径20-30 nm)。通过FT-IR,紫外可见光谱和X射线衍射图表征了POT / c-MWNT复合材料的结构。相对于不含c-MWNTs的POT,POT / c-MWNT复合材料的电导率有所提高。

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