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首页> 外文期刊>Micro & Nano Letters, IET >Preparation and characterisation of Cu2FeSnS4 microano particles by a liquid reflux method
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Preparation and characterisation of Cu2FeSnS4 microano particles by a liquid reflux method

机译:液相回流法制备Cu 2 FeSnS 4 微/纳米粒子及其表征

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摘要

Quaternary compounds Cu2FeSnS4 (CFTS), a promising alternative material for solar cell absorber layer, were successfully synthesised by a liquid reflux method in a mixture solvent of triethylenetetramine-ethylene glycol (TETA-EG, 1:1, v/v) at 230°C for 3 h under the atmospheric pressure condition. The phase, micro-structure, morphology, chemical composition and optical properties of the as-synthesised CFTS microano particles were characterised using X-ray diffraction, scanning electron microscopy, energy dispersive X-ray spectrometry and ultraviolet-visible absorption spectrophotometer. The results showed that the stannite structured CFTS microano particles with close to theoretical stoichiometric ratio were pure and well-crystallised, the particle size ranged from 70 to 240 nm and the particles were well-distributed, the band gap was about 1.25 eV which indicated its suitable application as the absorption layer of thin film solar cells.
机译:在三亚乙基四胺-乙二醇(TETA-EG,1:1,v / v)的混合溶剂中,通过液体回流法成功地合成了四元化合物Cu2FeSnS4(CFTS),它是太阳能电池吸收层的有希望的替代材料。在大气压条件下保持3小时。利用X射线衍射,扫描电子显微镜,能量色散X射线能谱和紫外可见吸收分光光度计对合成的CFTS微/纳米颗粒的相,微结构,形态,化学组成和光学性质进行了表征。结果表明,具有接近理论化学计量比的锡矿结构CFTS微/纳米粒子是纯净且结晶良好的,粒径范围为70-240 nm,粒子分布均匀,带隙约为1.25 eV,指出其适合用作薄膜太阳能电池的吸收层。

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