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首页> 外文期刊>Molecular Crystals and Liquid Crystals >Photovoltaic Properties of Poly(Carbazolyl-2,7-vinylene) Derivatives by Optimization of Cathode Structures
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Photovoltaic Properties of Poly(Carbazolyl-2,7-vinylene) Derivatives by Optimization of Cathode Structures

机译:阴极结构优化对聚咔唑-2,7-亚乙烯基衍生物的光伏性能

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摘要

The novel π-conjugated polymer, poly[N-(3,4-bis(decyloxy)phenyl)carbazolyl-2,7-vinylene)-co-{2-methoxy-5-(2-ethylhexyloxy)-1,4-phenylenevinylene}] (PCzV-co-MEH-PPV) was synthesized by using the Gilch polymerization method and used for the fabrication efficient photovoltaic cells. Bulk heterojunction photovoltaic cells, ITO/PEDOT:PSS/polymer:PC61BM (1:3, 1:4, 1:5 and 1:6 wt/wt)/Ca/Al configurations, were fabricated by blending of the PCzV-co-MEH-PPV with the fullerene derivative [6,6]-phenyl C61 butyric acid methyl ester (PCBM) were found to have a power conversion efficiency > of up to 1.33%, measured using an AM 1.5 G solar simulator at 100 mW/cm2 light illumination.
机译:新型π共轭聚合物,聚[N-(3,4-双(癸氧基氧基)苯基)咔唑基-2,7-亚乙烯基)-co- {2-甲氧基-5-(2-乙基己氧基)-1,4 -通过使用Gilch聚合方法合成了(PCzV-co-MEH-PPV),并将其用于制造有效的光伏电池。 ITO / PEDOT:PSS /聚合物:PC 61 BM(1:3、1:4、1:5和1:6 wt / wt)/ Ca / Al构型的大块异质结光伏电池通过使用AM测量,将PCzV-co-MEH-PPV与富勒烯衍生物[6,6]-苯基C61丁酸甲酯(PCBM)混合制备的功率转换效率>高达1.33% 1.5 G太阳模拟器,光照100 mW / cm 2

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