Hydrothermal syntheses and structural characterization of zeolite analogue compounds based on cobalt phosphate

Pingyun Feng; Xianhui Bu; Galen D. Stucky

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Hydrothermal syntheses and structural characterization of zeolite analogue compounds based on cobalt phosphate

机译：基于磷酸钴的沸石类似物的水热合成及结构表征

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Zeolite analogues containing transition metals are highly desirable for Industrial processes. A generalized synthesis method has been developed and demonstrated to have the potential to generate many transition-metal-rich zeolite-type structures. The method has been used to make zeolite analogues based on cobalt phosphate with diverse chemical compositions and structure types, Including some analogues never previously synthesized and some zeolite-like structures only previously known theoretically. The concentrations of transition-metal atoms In the frameworks can be controlled by varying the charge and geometry of the structure-directing amine molecules.

机译：含有过渡金属的沸石类似物是工业过程中非常需要的。已经开发出一种通用的合成方法，并证明其具有产生许多富含过渡金属的沸石型结构的潜力。该方法已被用于制备具有多种化学组成和结构类型的基于磷酸钴的沸石类似物，包括一些以前从未合成的类似物和一些理论上仅已知的类似沸石的结构。骨架中过渡金属原子的浓度可以通过改变结构胺分子的电荷和几何形状来控制。

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《Nature》 |1997年第6644期|p.735-741|共7页
作者
Pingyun Feng; Xianhui Bu; Galen D. Stucky;
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收录信息美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);美国《化学文摘》(CA);
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正文语种 eng
中图分类自然科学总论;
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3. Hydrothermal syntheses and structural characterization of two organic-inorganic hybrid compounds based on Lindqvist polyanions [J] . Pengtao Maa Chunfa Yua Junwei Zhaoa Yuquan Fenga Jingping Wanga* amp, Jingyang Niua* Journal of Co-ordination Chemistry . 2009,第19期

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4. Hydrothermal Syntheses and Structural Characterizations of Lanthanide-ContainingCoordination Polymers Constructed by Orotic Acid [C] . International symposium on solid state chemistry in China amp; 8th Chinese national conference on solid state chemistry and inorganic synthesis : Book of abstracts . 2002

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Hydrothermal syntheses and structural characterization of zeolite analogue compounds based on cobalt phosphate

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